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Mineralogical and chemical characterization of sepiolite occurrences at Karapinar, Konya Basin, Turkey

N. Karakaya, M. Celik Karakaya, A. Temel, S. Kupeli and C. Tunoglu
Mineralogical and chemical characterization of sepiolite occurrences at Karapinar, Konya Basin, Turkey
Clays and Clay Minerals (August 2004) 52 (4): 495-509

Abstract

The Konya region in central Anatolia is covered by Pliocene-Late Pleistocene sediments and volcanites related to the sediments NNW of Karapmar, Turkey. In the area, the Upper Miocene-Quaternary Uzecek Dagi and Karacadag volcanites are generally of the same age and formed from magmas of similar composition. The Karapinar formation is brown to whitish-beige, partly fossiliferous and consists of limestone, marl, claystone and, locally, sandy layers. Silica-rich lenses, nodules and layers are observed in the upper strata which locally contain sepiolite-rich layers. The mineralogical composition of sepiolite samples taken from the area was determined by powder X-ray diffractometry, while the abundance of major-element oxides was measured by X-ray fluorescence spectrometry. The crystallographic and morphological properties of samples were determined by means of scanning electron microscopy and energy dispersive spectroscopy. Samples were taken from three sections and from random locations. Mineral assemblages in the same stratigraphic position are generally similar in the three sections, while the thickness of the individual beds varies between the sections. Dolomite and calcite are the main carbonate minerals in the sections. Sepiolite occurs primarily with dolomite and, locally, dolomite and calcite, and less commonly with just calcite. Generally, quartz, feldspar and mica are found, especially in the upper parts of the sections where tuff is abundant. CaO and MgO dominate the major-element oxides. The CaO content is between 1 and 30% while MgO is 3-21%. Al (sub 2) O (sub 3) and SiO (sub 2) are generally higher in the sepiolitic and tuffitic layers. Al (sub 2) O (sub 3) is <3% and SiO (sub 2) is between 15-18% in the sepiolitic layers. The average structural formula of sepiolite was calculated as: (Mg (sub 7.00) Al (sub 0.44) Fe (sub 0.18) ) (Si (sub 11.71) Al (sub 0.29) )O (sub 30) (OH) (sub 4) (OH (sub 2) ) (sub 4) Ca (sub 0.13) K (sub 0.09) Na (sub 0.01) . Sepiolite occurs as fibers and dolomite as subhedral or euhedral crystals. It is considered that sepiolite was formed either by conversion of dolomite or by direct precipitation from solution under alkaline and saline conditions in the Karapinar paleolake. The paleolake was saturated with respect to Mg, Ca and Si derived from groundwater that percolated along fracture systems.


ISSN: 0009-8604
EISSN: 1552-8367
Coden: CLCMAB
Serial Title: Clays and Clay Minerals
Serial Volume: 52
Serial Issue: 4
Title: Mineralogical and chemical characterization of sepiolite occurrences at Karapinar, Konya Basin, Turkey
Affiliation: Selcuk Universitesi, Jeoloji Muhendisligi Bolumu, Konya, Turkey
Pages: 495-509
Published: 200408
Text Language: English
Publisher: Clay Minerals Society, Clarkson, NY, United States
References: 46
Accession Number: 2005-000644
Categories: Sedimentary petrology
Document Type: Serial
Bibliographic Level: Analytic
Illustration Description: illus. incl. 3 tables, sketch map
N37°00'00" - N39°19'60", E32°00'00" - E35°00'00"
Secondary Affiliation: Hacettepe Universitesi, TUR, Turkey
Country of Publication: United States
Secondary Affiliation: GeoRef, Copyright 2017, American Geosciences Institute.
Update Code: 200501
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