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The low-temperature (T<120 degrees C) H (sub 2) O-RbCl phase diagram comparison with other water-alkali chloride systems
Index Terms/Descriptors
Abstract
The eutectic T in the H (sub 2) O-RbCl system was determined from synthetic fluid inclusions, using a 39.99 + or - 0.01 wt.% RbCl solution. By isolating the last solid (RbCl) and freezing the remaining liquid, the T at which the liquid begins to melt was accurately measured (-16.4 + or - 0.1 degrees C) during subsequent heating measurements. The ice-melting and salt-melting curves were fitted using a constrained least-squares procedure and the eutectic composition was calculated (39.55 + or - 0.01 wt.% RbCl). The phase diagram is similar to those of H (sub 2) O-KCl and H (sub 2) O-CsCl systems, but differs from those including the smallest alkali ions (LiCl and NaCl) which are complicated by the occurrence of hydrates.
ISSN: 0935-1221
Serial Title: European Journal of Mineralogy
Serial Volume: 9
Serial Issue: 5
Title: The low-temperature (T<120 degrees C) H (sub 2) O-RbCl phase diagram comparison with other water-alkali chloride systems
Affiliation: Universite de Lille I, Sedimentologie et Geodynamique,
Villeneuve d'Ascq,
France
Pages: 987-992
Published: 199710
Text Language: English
Publisher: Schweizerbart'sche Verlagsbuchhandlung (Naegele u. Obermiller),
Stuttgart,
Federal Republic of Germany
References: 23
DOI:
10.1127/ejm/9/5/0987
Accession Number: 1997-077048
Categories: Mineralogy of non-silicates
Document Type: Serial
Bibliographic Level: Analytic
Illustration Description: 1 table
Secondary Affiliation: Centre de Recherches Petrographiques et Geochimiques,
FRA,
FranceE.N.S.G.,
FRA,
FranceUniversidad Nacional Autonoma de Mexico,
MEX,
Mexico
Country of Publication: Germany
Secondary Affiliation: GeoRef, Copyright 2017, American Geosciences Institute. Reference includes data from Mineralogical Abstracts, United KingdomTwickenhamUKUnited Kingdom
Update Code: 199724