Carbon isotopic vital effect and organic diagenesis, Lower Cambrian Forteau Formation, Northwest Newfoundland; implications for delta (super 13C) chemostratigraphy

Lithology and diagenesis are important components in delta (super 13) C (sub carb) stratigraphic variation in Lower Cambrian Forteau Formation limestones. The delta (super 13) C values of ooids indicate that shallow seawater Sigma CO (sub 2) was -1.0ppm to 0.0ppm. Salterella and archaeocyathans probably exerted a vital effect on the carbon isotopic composition of their skeletal CaCO (sub 3) . The diversification of early skeletal organisms complicated the biogeochemical cycling of carbon isotopes during the Precambrian-Cambrian transition, making delta (super 13) C chemostratigraphy and isotopic mass-balance calculations more difficult in Lower Cambrian and younger deposits. Similar studies should be carried out on other Lower Cambrian sections before the carbon isotopic chemostratigraphic technique can be validated for this important interval.