We report the first find of Al-rich chromitites in the Nuasahi massif located in the Singhbhum Craton, eastern India. Electron microprobe analyses yielded Al2O3 contents between 19.86 and 25.86 wt%. The Cr2O3 and Fe2O3 concentrations vary (in wt %) from 34.8 to 40.67 and 5.38 to 7.05, respectively. TiO2 content ranges from 0.04 to 0.71 wt%. The silicates interstitial to chromite consist of enstatite, magnesiohornblende and clinochlore. One sample contains 855 ppb of total platinum-group elements (PGE) and shows a chondrite-normalized PGE pattern with a slightly positive slope, with enrichment in Pt and Pd relative to Os and Ir. Ruthenium and Rh show positive and negative peaks, respectively. In agreement with the PGE distribution, the following platinum-group minerals (PGM) have been found: laurite ((Ru,Os)S2), erlichmanite ((Os,Ru)S2), irarsite (IrAsS), vysotskite ((Pd,Ni)S), braggite or cooperite ((Pt,Pd,Ni)S) and Pd-telluride. The PGM form small grains, less than 10 μm across, and occur associated with base metal sulphides (BMS) and rutile included in magmatic minerals, such as chromite and enstatite. The BMS occur exclusively included in chromite. Mineralogical observations suggest that the (Os, Ir, Ru), Pt- and Pd-bearing phases crystallized in the magmatic stage, before or during the precipitation of the host chromite, under relatively high sulphur fugacity. Part of the Pd, together with Te, was initially enclosed at high temperature as small clusters in the sulphide liquid and then incorporated in the crystallizing BMS. Finally, these elements precipitated as Pd-telluride blebs, as an exsolution product at lower temperatures. Rutile occurs as a minor phase in association with PGM, included in chromite or in the contact chromite–silicate. The mode of occurrence of rutile in the Nuasahi chromitite is similar to that reported from the stratiform chromitites emplaced in stable cratonic settings.
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Research Article|
August 01, 2017
Platinum-group minerals (PGM) in the chromitite from the Nuasahi massif, eastern India: further findings and implications for their origin
Federica Zaccarini;
1
Department of Applied Geology and Geophysics, University of Leoben, Peter Tunner Str. 5, 8700 Leoben, Austria*
Corresponding author, e-mail: federica.zaccarini@unileoben.ac.at
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Krishnakanta A. Singh;
Krishnakanta A. Singh
2
Wadia Institute of Himalayan Geology, 33, General Mahadev Singh Road, Dehradun 248001, India
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Giorgio Garuti;
Giorgio Garuti
1
Department of Applied Geology and Geophysics, University of Leoben, Peter Tunner Str. 5, 8700 Leoben, Austria
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Manvalan Satyanarayanan
Manvalan Satyanarayanan
3
National Geophysical Research Institute, Uppal Road, Hyderabad 500007, India
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1
Department of Applied Geology and Geophysics, University of Leoben, Peter Tunner Str. 5, 8700 Leoben, Austria
Krishnakanta A. Singh
2
Wadia Institute of Himalayan Geology, 33, General Mahadev Singh Road, Dehradun 248001, India
Giorgio Garuti
1
Department of Applied Geology and Geophysics, University of Leoben, Peter Tunner Str. 5, 8700 Leoben, Austria
Manvalan Satyanarayanan
3
National Geophysical Research Institute, Uppal Road, Hyderabad 500007, India*
Corresponding author, e-mail: federica.zaccarini@unileoben.ac.at
Publisher: Deutsche Mineralogische Gesellschaft, Sociedad Española de Mineralogia, Societá Italiana di Mineralogia e Petrologia, Société Francaise de Minéralogie
Received:
17 Nov 2016
Revision Received:
09 Feb 2017
Accepted:
22 Feb 2017
First Online:
17 Nov 2017
Online ISSN: 1617-4011
Print ISSN: 0935-1221
© 2017 E. Schweizerbart’sche Verlagsbuchhandlung Science Publishers
E. Schweizerbart'sche Verlagsbuchhandlung Science Publishers
European Journal of Mineralogy (2017) 29 (4): 571–584.
Article history
Received:
17 Nov 2016
Revision Received:
09 Feb 2017
Accepted:
22 Feb 2017
First Online:
17 Nov 2017
Citation
Federica Zaccarini, Krishnakanta A. Singh, Giorgio Garuti, Manvalan Satyanarayanan; Platinum-group minerals (PGM) in the chromitite from the Nuasahi massif, eastern India: further findings and implications for their origin. European Journal of Mineralogy 2017;; 29 (4): 571–584. doi: https://doi.org/10.1127/ejm/2017/0029-2637
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Index Terms/Descriptors
- Asia
- base metals
- chromite
- chromitite
- chromium
- cooperite
- electron probe data
- enrichment
- exsolution
- igneous rocks
- India
- Indian Peninsula
- iridium
- iron
- laurite
- metal ores
- metals
- Orissa India
- osmium
- oxides
- palladium
- platinum
- platinum group
- plutonic rocks
- rhodium
- ruthenium
- rutile
- sulfides
- tellurides
- tellurium
- titanium
- ultramafics
- irarsite
- erlichmanite
- braggite
- vysotskite
- Singhbhum Craton
- Nuasahi Massif
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