Calcite dissolution on (101̄4) cleavage surface was investigated by means of ex situ vertical scanning interferometry (VSI) measurements using flow-through and batch experiments at ambient pCO2, pH 1–7 and room temperature in metal (Fe(II), Zn, Cu and Cd) and metal-free chloride solutions, and metal sulphate and metal-free sulphate solutions, undersaturated with respect to calcite and undersaturated or in equilibrium with respect to gypsum.
where aH+ is the proton activity and k2 equals 2.5 ± 0.8 × 10−11 mol cm−2 s−1. The rhombic etch pit morphology changes at very low pH (pH < 3) due to the catalytic effect of pH on calcite dissolution, yielding rounded pseudo-rhombic etch pits.
The presence of Fe(II), Cu, Zn and Cd inhibits calcite dissolution at pH 3, in contrast to the presence of sulphate, which does not affect calcite dissolution. The presence of Zn affected the etch pit morphology, yielding triangular etch pits. Under gypsum saturation conditions, gypsum (or other metal-bearing sulphate phases) precipitated on calcite as calcite dissolved, yielding a decrease in dissolution rate with time due to loss of calcite reactivity. Based on energy-dispersive X-ray fluorescence (EDXRF) measurements the precipitation rates of Zn4SO4(OH)6 · 5H2O and Cu4SO4(OH)6 · 2H2O were calculated to be between 1 × 10−7 and 6 × 10−7 mol m−2s−1.