Kravtsovite, PdAg2S, is a new platinum-group mineral discovered in the Komsomolsky mine of the Talnakh deposit, Noril’sk district, Russia. It forms equant inclusions (ranging in size from a few μm to 40–50 μm) in silicates and pyrite, commonly intergrown with vysotskite and Au–Ag alloy in aggregates (100–200 μm across) with telargpalite, cooperite, braggite, vysotskite, sopcheite, stibiopalladinite, sobolevskite, moncheite, kotulskite, malyshevite and insizwaite. Kravtsovite is brittle; it has a metallic lustre and a grey streak. In plane-polarised light, kravtsovite is yellowish white, has strong bireflectance, is strongly pleochroic in shades of slightly yellowish white to bluish grey, and exhibits a strong anisotropy with rotation tints of salmon-pink, orange, pale blue and dark blue–black. It exhibits no internal reflections. Reflectance values in air (R1, R2 in %) are: 32.2, 38.3 at 470, 31.6, 39.4 at 546, 30.2, 39.8 at 589 and 28.8, 41.1 at 650 nm. Eighteen electron probe microanalyses of kravtsovite give the average composition: Pd 30.53, Ag 60.11, S 8.47, and Se 0.74, total 99.85 wt%, corresponding to the empirical formula Pd1.03Ag1.99(S0.95Se0.03)Σ0.98 based on a total of 4 atoms per formula unit (apfu). The average of eight analyses on synthetic kravtsovite is: Pd 30.98, Ag 60.27, and S 8.81, total 100.07 wt%, corresponding to Pd1.04Ag1.99S0.98. The mineral is orthorhombic, space group Cmcm, with a 7.9835(1), b 5.9265(1), c 5.7451(1) Å, V 271.82(1) Å3 and Z = 4. The crystal structure was refined from the powder X-ray-diffraction data of the synthetic analogue. The strongest lines in the X-ray powder diffraction pattern of synthetic kravtsovite [d in Å (I) (hkl)] are: 2.632(51)(021), 2.458(65)(112), 2.4263(71)(310), 2.3305(60)(202), 2.2352(100)(311), 2.1973(48) (221), 2.0619(42)(022), 1.9172(30)(130), 1.3888(42)(240,332), 1.3586(28)(512). The mineral honours V.F. Kravtsov, one of the discoverers of the Talnakh and Oktyabrsk deposits in the Noril’sk district of Russia.
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Research Article|
August 01, 2017
Kravtsovite, PdAg2S, a new mineral from the Noril’sk-Talnakh deposit, Krasnoyarskiy kray, Russia
Anna Vymazalová;
1
Czech Geological Survey, Geologická 6, Prague 5, 152 00, Czech Republic*
Corresponding author, e-mail: [email protected]
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Frantisek Laufek;
Frantisek Laufek
1
Czech Geological Survey, Geologická 6, Prague 5, 152 00, Czech Republic
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Sergei F. Sluzhenikin;
Sergei F. Sluzhenikin
2
Institute of Geology of Ore Deposits, Mineralogy, Petrography and Geochemistry RAS, Staromonetnyi per. 12, Moscow, 119 017, Russia
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Chris J. Stanley;
Chris J. Stanley
3
Department of Earth Sciences, Natural History Museum, London, SW7 5BD, UK
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Vladimir V. Kozlov;
Vladimir V. Kozlov
4
Oxford Instruments (Moscow Office), 26, Denisovskii Pereulok, Moscow, 105005, Russia
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Dmitry A. Chareev;
Dmitry A. Chareev
5
Institute of Experimental Mineralogy RAS, Chernogolovka, 142432, Russia
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Maria L. Lukashova
Maria L. Lukashova
6
Tescan CIS Ltd., Grazhdansky pr. 11, St. Petersburg, 195220, Russia
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Frantisek Laufek
1
Czech Geological Survey, Geologická 6, Prague 5, 152 00, Czech Republic
Sergei F. Sluzhenikin
2
Institute of Geology of Ore Deposits, Mineralogy, Petrography and Geochemistry RAS, Staromonetnyi per. 12, Moscow, 119 017, Russia
Chris J. Stanley
3
Department of Earth Sciences, Natural History Museum, London, SW7 5BD, UK
Vladimir V. Kozlov
4
Oxford Instruments (Moscow Office), 26, Denisovskii Pereulok, Moscow, 105005, Russia
Dmitry A. Chareev
5
Institute of Experimental Mineralogy RAS, Chernogolovka, 142432, Russia
Maria L. Lukashova
6
Tescan CIS Ltd., Grazhdansky pr. 11, St. Petersburg, 195220, Russia*
Corresponding author, e-mail: [email protected]
Publisher: Deutsche Mineralogische Gesellschaft, Sociedad Española de Mineralogia, Societá Italiana di Mineralogia e Petrologia, Société Francaise de Minéralogie
Received:
18 Jan 2017
Revision Received:
10 Mar 2017
Accepted:
27 Mar 2017
First Online:
17 Nov 2017
Online ISSN: 1617-4011
Print ISSN: 0935-1221
© 2017 E. Schweizerbart’sche Verlagsbuchhandlung Science Publishers
E. Schweizerbart'sche Verlagsbuchhandlung Science Publishers
European Journal of Mineralogy (2017) 29 (4): 597–602.
Article history
Received:
18 Jan 2017
Revision Received:
10 Mar 2017
Accepted:
27 Mar 2017
First Online:
17 Nov 2017
Citation
Anna Vymazalová, Frantisek Laufek, Sergei F. Sluzhenikin, Chris J. Stanley, Vladimir V. Kozlov, Dmitry A. Chareev, Maria L. Lukashova; Kravtsovite, PdAg2S, a new mineral from the Noril’sk-Talnakh deposit, Krasnoyarskiy kray, Russia. European Journal of Mineralogy 2017;; 29 (4): 597–602. doi: https://doi.org/10.1127/ejm/2017/0029-2653
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Index Terms/Descriptors
- alloys
- Asia
- brittle materials
- Commonwealth of Independent States
- crystal structure
- electron probe data
- formula
- inclusions
- intergrowths
- Krasnoyarsk Russian Federation
- mineral inclusions
- new minerals
- Norilsk Russian Federation
- optical properties
- physical properties
- refinement
- reflectance
- Russian Federation
- Taymyr Dolgan-Nenets Russian Federation
- X-ray diffraction data
- vysotskite
- Talnakh Deposit
- Komsomolsky Mine
- kravtsovite
Latitude & Longitude
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