ABSTRACT

Bernard Kübler measured illite ‘crystallinity’, the half-height width or full width at half maximum (FWHM) of the X-ray diffraction line of illite/mica at 10 Å, directly on the diffraction traces; this procedure has since been followed by the vast majority of workers. However, some workers have recently measured the FWHM of the fitted Pearson VII function rather than on the diffraction traces. The FWHM of this function for low-angle phyllosilicate diffraction peaks (FWHM*PVII) is almost consistently ‘broader’ than those measured directly on the diffraction trace profiles (FWHMtrace) by up to 0.08°Δ2θ for the broader peaks. The Pearson VII function shows gentle curvature (‘smoothing’) at its tops and fast fading of the tails relative to virtually all 10 Å diffraction traces. The broad FWHM*PVII results from the consequent lowering/’under-fitting’ of the peak tops and the upper tails and compensatory broadening/’over-fitting’ of the intermediate peak flanks. FWHM*PVII ‘contraction’ with respect to FWHMtrace and enhancement of the peak maximum is found on traces of muscovite strips. The fitting reliabilities of the Cauchy function are almost invariably better than those of the Pearson VII function. Their FWHM*Cauchy values are narrower for both the illite/mica 10 Å and the chlorite 7 Å reflections; although they still differ somewhat from the FWHMtrace, they are much closer, usually within 0.02°Δ2θ. This markedly lesser broadening of FWHM* of the Cauchy of the Pearson VII function is the result of its stronger top curvature and notably faster tail fading (less ‘smoothening’). For higher-angle mica peaks, the FWHM* values of the Pearson VII and Cauchy functions converge, usually differing only by 0.01–0.03°Δ2θ for the 5 Å peak, and even less for the 3.3 Å peak. It is therefore strongly recommended that FWHM values of the illite/mica 10 Å reflections be measured on the diffraction traces rather than on fitted functions. Where peak fitting is unavoidable (e.g. in order to separate the contributions of adjoining, partly resolved or unresolved reflections on broadened 10 Å reflections), Cauchy rather than Pearson VII functions should be used.

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