By examining the minor and trace element contents of chromites from three intrusions—the Bushveld Complex (South Africa), the Stillwater Complex (USA), and the Great Dyke (Zimbabwe)—and comparing these chromite compositions with those of magmas from which they could have formed (komatiites and picrites) we conclude that (i) the variations in Ti, V, Sc, and Ga contents across stratigraphy and across individual layers do not support the model of magma mixing leading to chromite-only crystallization, (ii) the chromites from the lowest levels of the intrusions could have crystallized from komatiite liquids that were contaminated with continental crust, (iii) the Great Dyke chromites have the highest Cr# and lowest incompatible element contents and formed from a liquid closest to komatiite, (iv) all of the chromites, except those of the Dunite Succession of the Great Dyke have equilibrated with a liquid that also had crystallized pyroxene, (v) the Great Dyke and Stillwater chromites show a narrower range in composition than the Bushveld chromites, and (vi) Chromites from the western limb of the Bushveld Complex contain much higher V contents than all the other chromites. This requires either, that the oxygen fugacity (fO2) was lower in the western Bushveld or that the chromites equilibrated with a V-rich magma. We favor a model where chromite and silicate minerals crystallized in cotectic proportions (∼2:98). The chromite, silicates, and transporting liquid are emplaced into the magma chamber. During emplacement the chromite and silicate separated due to viscous particle flow to form a massive chromite layer overlain by silicates.
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Research Article|
November 02, 2022
A comparison of trace element concentrations in chromite from komatiites, picrites, and layered intrusions: implications for the formation of massive chromite layers
Sarah-Jane Barnes;
a
Sciences de la Terre, Université du Québec à Chicoutimi, 555 boulevard de l’université, QC G7H 2B1, CanadaCorresponding author: Sarah-Jane Barnes (email: sjbarnes@uqac.ca)
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Eduardo T. Mansur;
Eduardo T. Mansur
a
Sciences de la Terre, Université du Québec à Chicoutimi, 555 boulevard de l’université, QC G7H 2B1, Canadab
Geological Survey of Norway, P.O. Box 6315 Torgarden, NO-7491, Trondheim, Norway
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Wolfgang D. Maier;
Wolfgang D. Maier
c
School of Earth and Environmental Sciences, Cardiff University, Cardiff, United Kingdom
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Stephen A. Prevec
Stephen A. Prevec
d
Department of Geology, Rhodes University, Makhanda, 6140, South Africa
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a
Sciences de la Terre, Université du Québec à Chicoutimi, 555 boulevard de l’université, QC G7H 2B1, Canada
Eduardo T. Mansur
a
Sciences de la Terre, Université du Québec à Chicoutimi, 555 boulevard de l’université, QC G7H 2B1, Canadab
Geological Survey of Norway, P.O. Box 6315 Torgarden, NO-7491, Trondheim, Norway
Wolfgang D. Maier
c
School of Earth and Environmental Sciences, Cardiff University, Cardiff, United Kingdom
Stephen A. Prevec
d
Department of Geology, Rhodes University, Makhanda, 6140, South AfricaCorresponding author: Sarah-Jane Barnes (email: sjbarnes@uqac.ca)
Publisher: Canadian Science Publishing
Received:
27 May 2022
Accepted:
24 Oct 2022
Accepted Manuscript:
02 Nov 2022
First Online:
09 Mar 2023
Online ISSN: 1480-3313
Print ISSN: 0008-4077
The Author(s)
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Canadian Journal of Earth Sciences (2023) 60 (2): 97–132.
Article history
Received:
27 May 2022
Accepted:
24 Oct 2022
Accepted Manuscript:
02 Nov 2022
First Online:
09 Mar 2023
Citation
Sarah-Jane Barnes, Eduardo T. Mansur, Wolfgang D. Maier, Stephen A. Prevec; A comparison of trace element concentrations in chromite from komatiites, picrites, and layered intrusions: implications for the formation of massive chromite layers. Canadian Journal of Earth Sciences 2022;; 60 (2): 97–132. doi: https://doi.org/10.1139/cjes-2022-0064
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