The Steptoean Positive Isotopic Carbon Excursion, or SPICE event, was a globally recorded +2‰ to +6‰ shift in δ13C values during the later Cambrian (ca. 500 Ma). The excursion is associated with regional sea level change and trilobite extinctions documented from multiple paleocontinents, yet the mechanism(s) for these events and the excursion itself are not fully understood. Recent studies have suggested that the SPICE is accompanied by global changes in redox conditions, which may have served as an extinction driver. Here, we present new geochemical and mineralogical data from an outcrop of the SPICE located along the Port au Port Peninsula in western Newfoundland. We focus on paired sedimentary mercury and glauconite enrichments as a potential redox indicator in an effort to evaluate local redox conditions during the SPICE in Newfoundland and assess the validity of Hg as a redox proxy. These strata record small mercury enrichments (<20 ppb) relative to SPICE background, sometimes coupled with elevated glauconite abundance. This coupling occurs after the carbon isotope peak, suggesting that the environment during the falling limb of SPICE experienced redox oscillations. Findings from this study supplement existing global proxies by adding information on redox conditions during the SPICE in a shallow shelf environment. Further, the coupling of Hg enrichments with elevated glauconite provides some support for the use of sedimentary Hg as a redox indicator when enrichments are elevated compared to background.
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Research Article|
March 08, 2022
Sedimentary mercury as a proxy for redox oscillations during the Cambrian SPICE event in western Newfoundland
Amy P.I. Hagen;
(Conceptualization, Investigation, Formal analysis, Writing – original draft, Writing – review & editing)
a
Department of Geosciences, Smith College, Northampton, MA 01063, USACorresponding author: Amy P.I. Hagen (email: amyhagen@vt.edu)
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David S. Jones;
David S. Jones
(Methodology)
b
Department of Geology, Amherst College, Amherst, MA 01002, USA
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Nicholas J. Tosca;
Nicholas J. Tosca
(Methodology)
c
Department of Earth Sciences, University of Cambridge, Cambridge CB2 3EQ, United Kingdom
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David A. Fike;
David A. Fike
(Methodology, Writing – review & editing)
d
Department of Earth and Planetary Sciences, Washington University in St. Louis, St. Louis, MO 63130, USA
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Sara B. Pruss
Sara B. Pruss
(Conceptualization, Funding acquisition, Methodology, Investigation, Writing – original draft, Writing – review & editing)
a
Department of Geosciences, Smith College, Northampton, MA 01063, USA
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Amy P.I. Hagen
Conceptualization, Investigation, Formal analysis, Writing – original draft, Writing – review & editing
a
Department of Geosciences, Smith College, Northampton, MA 01063, USA
David S. Jones
Methodology
b
Department of Geology, Amherst College, Amherst, MA 01002, USA
Nicholas J. Tosca
Methodology
c
Department of Earth Sciences, University of Cambridge, Cambridge CB2 3EQ, United Kingdom
David A. Fike
Methodology, Writing – review & editing
d
Department of Earth and Planetary Sciences, Washington University in St. Louis, St. Louis, MO 63130, USA
Sara B. Pruss
Conceptualization, Funding acquisition, Methodology, Investigation, Writing – original draft, Writing – review & editing
a
Department of Geosciences, Smith College, Northampton, MA 01063, USACorresponding author: Amy P.I. Hagen (email: amyhagen@vt.edu)
Publisher: Canadian Science Publishing
Received:
06 Oct 2021
Accepted:
14 Feb 2022
First Online:
03 Oct 2022
Online ISSN: 1480-3313
Print ISSN: 0008-4077
The Author(s)
Permission for reuse (free in most cases) can be obtained from copyright.com.
Canadian Journal of Earth Sciences (2022) 59 (8): 504–520.
Article history
Received:
06 Oct 2021
Accepted:
14 Feb 2022
First Online:
03 Oct 2022
Citation
Amy P.I. Hagen, David S. Jones, Nicholas J. Tosca, David A. Fike, Sara B. Pruss; Sedimentary mercury as a proxy for redox oscillations during the Cambrian SPICE event in western Newfoundland. Canadian Journal of Earth Sciences 2022;; 59 (8): 504–520. doi: https://doi.org/10.1139/cjes-2021-0108
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Index Terms/Descriptors
- C-13/C-12
- Cambrian
- Canada
- carbon
- chemical composition
- chemostratigraphy
- coastal environment
- Eastern Canada
- Eh
- glauconite
- isotope ratios
- isotopes
- lithostratigraphy
- mercury
- metals
- mica group
- Newfoundland
- Newfoundland and Labrador
- paleoenvironment
- Paleozoic
- petrography
- Port au Port Peninsula
- sheet silicates
- silicates
- stable isotopes
- Steptoean
- subtidal environment
- Upper Cambrian
- X-ray diffraction data
- Petit Jardin Formation
- Man O'War Member
- Felix Member
Latitude & Longitude
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