Abstract

The optical absorption spectra of green vesuvianite crystals from Lowell County, Vermont, are reported in the energy range 12 000 cm−1 to 30 000 cm−1. The principal absorptions have been attributed to octahedrally bonded Fe3+ and the individual bands have been assigned to spin-forbidden electronic transitions from the 6A1 ground state to excited states in Fe3+. In particular, the 6A1 → 4A14E(G) transition is marked by a relatively sharp band at 21 600 cm−1.

You do not currently have access to this article.