Abstract Colmenar Limestone is one of the traditional materials most commonly used in monuments in Madrid, Spain. The petrophysical properties of this stone determine its high resistance to decay. Its low water absorption and pore size distribution favour good hydraulic behaviour, which is likewise furthered by its high ultrasound velocity and low anisotropy. The durability findings pursuant to the 280 freeze–thaw, 42 thermal shock, 30 salt crystallization and 120 salt mist cycles conducted confirmed the stone’s resistance to decay in these simulated aggressive environments. The mass loss recorded in the samples and the variation in petrophysical parameters were generally very low after all except the salt crystallization trials, which induced loss of cohesion on the stone surface, increased roughness and the formation of concentric microcracks, sub-parallel to the more exposed surface, that also affected the arris and vertices of the specimens tested.

Abstract This paper discusses the research conducted prior to restoring the ‘Don Pedro I’ facade on the Real Alcázar or royal palace at Seville, Spain. The different types of stone on the facade were located and characterized, and their state of decay mapped. Although other materials (brick, rendering, ceramics, marble) are present on the facade, its main elements are made from two types of limestone: palomera and tosca , each in a different state of conservation and exhibiting distinct behaviour. Colour parameters, real and bulk densities, compactness, open porosity, water saturation coefficient and total porosity were determined to characterize the two varieties. In addition, ultrasonic techniques were used to map the various levels of decay on the facade, stone by stone, for future interventions. The findings show that owing to its petrographical and petrophysical properties, palomera stone is of a lower quality than tosca stone, and has undergone more intense deterioration.

Abstract The historic treatment of stonework has often been linked to the artificial application of patinas, mainly for aesthetic and protective reasons. Increasingly, however, researchers have identified a possible combined origin for patinas that has linked natural, biological processes to those associated with an artificial, man-made origin. This suggests that, although coatings may have been initially applied on purpose, they transform over time with the aid of micro-organisms and other chemical interactions. The original mixture applied to create a patina could include lime and/or gypsum, water, natural pigments and organic additives. However, their present-day mineralogy is varied and includes a wide range of minerals from calcium carbonates to calcium sulphates, calcium oxalates, calcium phosphates, silicates (quartz, feldspar, clay minerals) and iron oxides/hydroxides. Patinas have been studied in detail in Greece and Italy, but rarely in Spain. In this paper, existing knowledge on Spanish patinas is co-ordinated and previous and current research summarized. Emphasis is placed on artificial patinas initially applied to protect stone. These both appear to effectively protect the stone substrates on which they were applied and provide an insight into historical techniques of stone conservation. Because of this their preservation should be a strong consideration in restoration projects. Ongoing research focuses on the challenges of reproducing patinas, based on historical references.

Abstract The palace of Nuevo Baztán is a state-designated historic monument in central Spain built in the early eighteenth century. The main building material used in its facades is limestone. The aim of this investigation was to characterize the limestone, defining deterioration mechanisms contributing to the decay of the stone facades and testing a series of potential preservation treatments. The limestone is a biosparite; two microfacies were identified according to microscopic differences (limestones A and B) with distinct petrophysical characteristics mainly due to their different pore systems. Primary deterioration mechanisms were identified as those related to cycles of thermal and hygric stress, biodeterioration and those associated with structural movements. Main decay forms in the surface of the stone are erosion with material loss, spalling and flaking, chromatic alteration, fissures and biodeterioration. Conservation products prossessing water-repellent properties were therefore considered. From an initial selection of ten products, two siloxane-based products were ultimately determined to be the most effective on the basis of chromatic variables, water vapour permeability, water-stone contact angle, scanning electron microscope observations and durability (artificial ageing tests). Both products reduce water absorption rates and are expected to slow the rate of limestone decay. This study also demonstrates the value of advance testing of potential treatment methods before application in the field.