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NARROW
Abstract Basin modelling tools are now more efficient to reconstruct palinspastic structural cross sections and compute the history of temperature, pore-fluid pressure and fluid flow circulations in complex structural settings. In many cases and especially in areas where limited erosion occurred, the use of well logs, bottom hole temperatures (BHT) and palaeo-thermometers such as vitrinite reflectance (Ro) and Rock-Eval (Tmax) data is usually sufficient to calibrate the heat flow and geothermal gradients across a section. However, in the foothills domains erosion is a dominant process, challenging the reconstruction of reservoir rocks palaeo-burial and the corresponding calibration of their past thermal evolution. Often it is not possible to derive a single solution for palaeo-burial and palaeo-thermal gradient estimates in the foothills, if based solely on maturity ranks of the organic matter. Alternative methods are then required to narrow down the error bars in palaeo-burial estimates, and to secure more realistic predictions of hydrocarbon generation. Apatite fission tracks (AFT) can provide access to time–temperature paths and absolute ages for the crossing of the 120 °C isotherm and timing of the unroofing. Hydrocarbon-bearing fluid inclusions, when developing contemporaneously with aqueous inclusions, can provide a direct access to the pore-fluid temperature and pressure of cemented fractures or reservoir at the time of cementation and hydrocarbon trapping, on line with the tectonic evolution. Further attempts are also currently made to use calcite twins for constraining reservoir burial and palaeo-stress conditions during the main deformational episodes. Ultimately, the use of magnetic properties and petrographical measurements can also document the impact of tectonic stresses during the evolution of the layer parallel shortening (LPS). The methodology integrating these complementary constraints will be illustrated using reference case studies from Albania, sub-Andean basins in Colombia and Venezuela, segments of the North American Cordillera in Mexico and in the Canadian Rockies, as well as from the Middle East.
Calibration and comparison of etching techniques for apatite fission-track thermochronology
Abstract Understanding time–temperature histories using apatite fission-track thermochronology involves sample preparation, analysis and then thermal modelling using an appropriate annealing algorithm. A subtle point in this sequence is ascertaining that the sample preparation utilized is compatible with the methodology used in obtaining the data for constructing the annealing data set. This issue is important if one wishes to utilize the relatively new multikinetic annealing algorithm of Ketcham et al. that is implemented in their AFTSolve and HeFTy models which is based on a different etching recipe than those previously used. A preliminary calibration step involves comparing published etch pit diameters for a suite of samples with those analysed by an operator. Results show that the operator can reliably reproduce the calibration data set. We then report a laboratory experiment using samples from Finland and Spain that compares the results obtained using two different etching methodologies (7% nitric acid with qualitative etching conditions and 5.5 M nitric acid at constant conditions). The two raw data sets yield variable results. Comparing the two etching methodologies reveals the influence of this procedure on the kinetic parameter D par .