Abstract The Bou Azzer mining district in the central part of the Anti-Atlas belt, Morocco, is renowned worldwide for its serpentinized Neoproterozoic ophiolitic complex that hosts peculiar cobalt-dominated and nickel-rich Co–Ni–Fe arsenide and sulfarsenide deposits with significant credits of gold and copper. The Bou Azzer central mine and its satellite deposits, which are spatially associated with serpentinite bodies and tectonically controlled, generally form breccias at the contact between serpentinites and more competent rock types (e.g. diorite) but may also comprise anastomosing vein and tension gashes networks rooted in the serpentinites and breaching into the competent rocks. A consensus on a genetic model for Bou Azzer has not been reached given the most controversial and still highly debated topics dealing with the absolute age of mineralization, and the identification of the source(s) of metals and arsenic. Here, within the geological framework of the Bou Azzer window and the geodynamic history in the Anti-Atlas, we summarize the key features of ore mineralogy, textures, paragenetic sequence and district-scale metal zonation. Using knowledge based on the current state of research – until high-precision and robust geochronological data are produced and permit a refinement of the genetic model – the key parameters for the origin of the Bou Azzer ores are: (1) arsenides of Ni and Co, which are followed by Co–Ni-sulfarsenides and Cu-sulfides, initiating a sequence of mineralization with precipitation controlled by the parameters mentioned in (2)–(4); (2) hydrothermal high salinity fluids (>30 wt% total salt eq.) fostering leaching of Co and Ni from debated source rocks and their transport as highly soluble chloride complexes; (3) dilution and cooling of those fluids from <320 to <200°C; (4) variable redox conditions that would control the progressive oxidation of As from the arsenide stage (As 1− ) to the sulfarsenide stage (As 3+ ); (5) unlike Neoproterozoic metalliferous and As-rich black shales, serpentinites fail to convincingly stand as a robust source of As despite being a reasonable source rock for Ni and Co; (6) the controversial U–Pb and Sm–Nd dates of brannerite and carbonate, respectively, although arguing in favour of an Hercynian timing of mineralization, do not preclude the possibility of a primary Pan-African mineralization (<615 Ma) and/or at c. 540 Ma, followed by remobilization of a pre-existing mineralization during Hercynian events.

Abstract The newly discovered (1998) West Bleida gold mineralization (3 tonnes metal Au) lies west of the main Moroccan Bleida copper deposit (1981–1991) in the central Anti-Atlas (southern Morocco). It is hosted by metamorphosed and deformed mafic to intermediate volcanic rocks that are part of the Neoproterozoic tholeiitic volcanosedimentary series forming the stratigraphically upper part of the Bou Azzer ophiolite sequence. Strong sericitization and local silicification are associated with mineralization. These altered rocks represent a proximal hydrothermal alteration halo around the West Bleida ore zones. Normative chlorite characterizes the metamorphic assemblage away from the ore zones. Gold mineralization primarily occurs as deformed gold-bearing quartz veins and disseminations in Cu-rich chert zones (chalcopyrite–malachite), Fe-rich lithofacies and breccia zones. Gold is accompanied by small amounts of copper sulphides (<1% modal chalcopyrite). Scanning electron microscope–energy dispersive spectrometry analyses of gold grains from veins and disseminations reveal the presence of palladium as inclusions of Pd–As–Sb, Pd–Bi–Se and Pd–Te mineral phases. An electron microprobe study confirms the presence of two types of gold. The first is an alloy of Au–Ag–Pd, typically bordered by small grains of Pd and Bi (Te,Sb) phases and associated with a metamorphic assemblage. Isomertieite, Pd 11 (Sb 2 ,As 2 ), was identified as one of the phases. The second type of gold is electrum (10% Ag, 90% Au), which is always associated with fractures and occurs with hematite and white mica. Based on its form and habits, West Bleida gold reflects two distinct generations of fluid activity. The primary event precipitated Au–Ag–Pd alloys from Au–Pd-bearing hydrothermal fluids and produced auriferous quartz veins and disseminations within mafic rocks of the Bleida ophiolitic accretionary complex. It was structurally and lithologically controlled. This early event is preserved in the deeper (and thus fresher) zones more than 80 m below the surface. Intense tectonic overprinting obscures the genetic relationship between vein and disseminated styles of mineralization, both of which contain Pd-rich gold, but some of the auriferous quartz veins are observed to crosscut disseminated mineralization. Two possible hypotheses are considered: the pre-tectonic root of a volcanogenic massive sulphide system, or a late tectonic orogenic (mesothermal) deposit. The presence of Pd minerals and anomalous cobalt concentrations suggest a source in ultramafic rocks. The second event, characterized by inclusion-free electrum, occurred much later and represents the alteration and weathering of the primary Pd-rich gold assemblage by oxidizing surface fluids. It affected all mineralized units and structures to a depth of 80 m. This post-tectonic surficial alteration also caused leaching of Cu-sulphides, which may explain their low abundances in the upper parts of the ore zones.