Abstract Paleoproterozoic (Rhyacian) gold deposits of the Loulo district in western Mali contain >17 million ounces (Moz) Au and form part of the second most highly endowed region within West Africa. The deposits are located within siliciclastic, marble, and evaporitic rocks of the ca. 2110 Ma greenschist facies Kofi series, which were folded and inverted between ca. 2100 and 2070 Ma, prior to gold mineralization. Deposits at Yalea and Gounkoto are located along discontinuous, low-displacement, albite- and carbonate-altered shear zones, whereas Gara is confined to a tourmaline-altered quartz sandstone unit. Lodes typically plunge gently to moderately, reflecting the attitude of folds in the adjacent rocks and bends in the host shear zones, both of which influenced their location. Gold mineralization in the Loulo district was broadly synchronous with emplacement of the Falémé batholith and associated Fe skarn mineralization, which intrude and overprint the western margin of the Kofi series, respectively. However, hydrothermal fluids generated during metamorphic devolatilization of the Kofi series rocks appear responsible for gold mineralization, albeit within a district-wide thermal gradient associated with emplacement of the Falémé batholith. The regional-scale Senegal-Mali shear zone, commonly cited as an important control on the location of gold deposits in western Mali, is absent in the Loulo district.

Abstract The Kibali district in the Democratic Republic of Congo hosts the large Karagba-Chaffeur-Durba (KCD) deposit and smaller satellite deposits that together contained 20 million ounces (Moz) of gold when mining recommenced in 2013. An additional 3 Moz of gold was probably mined from the district before 2013. Gold deposits in the Kibali district are located along the KZ trend, a series of folds, contractional shear zones, and altered lithostratigraphic units that coincide with the margin of an earlier 2630 to 2625 Ma intraorogenic basin within the Neoarchean Moto belt. Fluids first responsible for barren carbonate-quartz-sericite alteration, and later for siderite and/or ankerite (±quartz, magnetite, pyrite, and/or chlorite) alteration with associated auriferous pyrite ± rare arsenopyrite veinlets, infiltrated and replaced the siliciclastic, banded iron formation (BIF), and chert host rocks via fold axes, shear zones, and reactive BIF horizons. The complex shape and gentle northeast plunge of the lodes across the Kibali district reflect the shape and plunge of coincident folds that formed during early barren alteration. Many other folded BIF horizons across the wider Moto belt remain barren or only weakly mineralized, suggesting deep extensional structures that may have developed in the vicinity of the KZ trend during basin opening and prior to gold mineralization, were important fluid pathways during later contractional deformation and mineralization.