Abstract Neoproterozoic successions are major hydrocarbon producers around the world. In North Africa, large basins with significant surface outcrops and thick sedimentary fills are widespread. These basins are now emerging as potential sources of hydrocarbons and are attracting interest from geological researchers in academia and the oil and gas industry. This volume focuses on recent developments in the understanding and correlation of North African basin fills and explores novel approaches to prospecting for source and reservoir rocks. The papers cover aspects of petroleum prospectivity and age-equivalent global petroleum systems, Neoproterozoic tectonics and palaeogeography, sequence stratigraphy, glacial events and global climatic models, faunal and floral evolution and the deposition of source rocks. The broader aim of this volume is to compare major environmental change, the emergence of life, the global carbon cycle and the implications for hydrocarbon exploration of well-studied Neoproterozoic successions worldwide.

Abstract The Neoproterozoic Eon is relatively poorly known from a petroleum perspective, despite the existence of producing, proven and potential plays in many parts of the world. In tectonic, climatic and petroleum systems terms, the Neoproterozoic to Early Cambrian period can be divided into three distinct phases: a Tonian to Early Cryogenian phase, prior to about 750 Ma, dominated by the formation, stabilization and initial break-up of the supercontinent of Rodinia; a mid Cryogenian to Early Ediacaran phase ( c . 750–600 Ma) including the major global-scale ‘Sturtian’ and ‘Marinoan’ glaciations and a mid Ediacaran to Early Cambrian ( c . post 600 Ma) phase corresponding with the formation and stabilization of the Gondwana Supercontinent. There is increasing evidence that deposition of many mid to late Neoproterozoic (to Early Palaeozoic) organic-rich units was triggered by strong post-glacial sea level rise on a global scale, following the ‘Snowball Earth’ type glaciations, coupled with basin development and rifting on a more local scale. Fieldwork in North Africa including the Taoudenni Basin in Mauritania, Algeria and Mali; the Anti-Atlas region of Morocco and the Cyrenaica, Kufra and Murzuk basins in Libya has added to the understanding of reservoir, source and seal relationships and confirmed the widespread presence of Precambrian stromatolitic carbonate units of potential reservoir facies. Current research on the chronostratigraphy, distribution and quality of source rocks, controls on reservoir quality and distribution of seals in the Precambrian–Early Cambrian hydrocarbon plays throughout South America, North Africa, the Middle East and the Indian Subcontinent is documented in this Special Publication.

Abstract The Infracambrian is a term for mostly Neoproterozoic successions in North Africa and areas to the east. Its base lies within the middle Neoproterozoic period, or Cryogenian, includes the youngest Neoproterozoic period, or Ediacaran, and continues into the early Cambrian to the level at which trilobites first appear. The Cryogenian lacks any biostratigraphic zonation; and no global biostratigraphic schemes exist for the Ediacaran. The formal classification of the Neoproterozoic is currently under review. The Cryogenian–Ediacaran (CE) interval includes at least three prominent diamictite horizons that are clearly linked to penecontemporaneous glaciations. The oldest is ‘Sturtian’, next oldest is ‘Marinoan’ (probably the most extensive), both names are Australian in origin but are used internationally. The Gaskiers glaciation is the youngest and probably the least extensive. There are important unresolved problems of the precise number, age, extent and nomenclature of the Neoproterozic glaciations in Australia. Several palaeomagnetic poles in the age range 600–550 Ma place glacial deposits of that age range in Australia in tropical latitudes. These data, together with older poles from Laurentia, gave rise to the notion of the Snowball Earth, in which the Earth froze over completely, but the profound refrigeration required appears to have had very little effect on biological evolution. Biostratigraphic zonation with the precision attainable throughout the Phanerozoic does not appear possible for the CE interval. Thus, most correlations are based on about 40 U–Pb and Re–Os dates. These confirm the existence of at least three glacial sequences (sequence is used here as an informal term), but it is possible that the Sturtian and Marinoan were essentially one glacial unit. Deglaciation was accompanied by the unique ‘cap carbonates’. The glacial sequences all show a characteristic δ 13 C pattern, but present knowledge is inadequate to use these patterns for detailed global correlation. The most reliable chemostratigraphic correlations are likely to be based on strontium isotope variations. Black shale horizons commonly follow deglaciation. A few basins produce Neoproterozoic hydrocarbons; others are potential producers. As a whole, the Neoproterozoic represents both a scientific and an exploration frontier.

Abstract Ecological and evolutionary principles are often context-dependent, particularly where the context is biologically defined. Organ-grade animals (eumetazoans) are particularly powerful contextual agents, with a unique capacity to drive escalatory co-evolution and build multi-tiered food-webs. The evolution of eumetazoans through the Ediacaran and early Cambrian fundamentally altered macroecological and macroevolutionary dynamics, including the structure and function of the marine carbon cycle. Pelagic eumetazoans can be held responsible for driving the evolution of relatively large eukaryotic phytoplankton, thereby shifting the system from a turbid, stratified, cyanobacteria-dominated stable state to the clear-water, well-oxygenated, algae-dominated condition typical of the Phanerozoic. Intermittent return to the pre-Ediacaran state during Phanerozoic extinctions and oceanic anoxic events suggests that the widespread anoxia detected in pre-Ediacaran deep-marine sequences may be a consequence of this alternate biological pump rather than a reflection of fundamentally lower levels of atmospheric oxygen. The transition between the pre- and post-Ediacaran states is also associated with the oldest commercially exploitable hydrocarbons, a possible by-product of invading animals and their top-down impact on the biological pump.

Abstract The plate tectonic and palaeogeographic history of the late Proterozoic is a tale of two supercontinents: Rodinia and Pannotia. Rodinia formed during the Grenville Event ( c . 1100 Ma) and remained intact until its collision with the Congo continent (800–750 Ma). This collision closed the southern part of the Mozambique Seaway, and triggered the break-up of Rodinia. The Panthalassic Ocean opened as the supercontinent of Rodinia split into a northern half (East Gondwana, Cathyasia and Cimmeria) and a southern half (Laurentia, Amazonia–NW Africa, Baltica, and Siberia). Over the next 150 Ma, North Rodinia rotated counter-clockwise over the North Pole, while South Rodinia rotated clockwise across the South Pole. In the latest Precambrian (650–550 Ma), the three Neoproterozoic continents – North Rodinia, South Rodinia and the Congo continents – collided during the Pan-Africa Event forming the second Neoproterozoic supercontinent, Pannotia (Greater Gondwanaland). Pan-African mountain building and the fall in sea level associated with the assembly of Pannotia may have triggered the extreme Ice House conditions that characterize the middle and late Neoproterozoic. Although the palaeogeographic maps presented here do not prohibit a Snowball Earth, the mapped extent of Neoproterozoic ice sheets favour a bipolar Ice House World with a broad expanse of ocean at the equator. Soon after it was assembled ( c . 560 Ma), Pannotia broke apart into the four principal Palaeozoic continents: Laurentia (North America), Baltica (northern Europe), Siberia and Gondwana. The amalgamation and subsequent break-up of Pannotia may have triggered the ‘Cambrian Explosion’. The first economically important accumulations of hydrocarbons are from Neoproterozoic sources. The two major source rocks of this age (Nepa of Siberia and Huqf of Oman) occur in association with massive Neoproterozoic evaporite deposits and in the warm equatorial–subtropical belt, within 30° of the equator.

Abstract Global correlations of Precambrian stratigraphic successions can be hampered by the coarse resolution of biostratigraphic and chemostratigraphic records, and by the scarcity of reliable U–Pb zircon age constraints. The development of the 187 Re (rhenium)– 187 Os (osmium) radioisotope system as an accurate deposition-age geochronometer for organic-rich sedimentary rocks (e.g. black shales) holds great potential for an improved radiometric calibration of the Precambrian rock record. Here, we review Re–Os isotope data obtained for Precambrian black shales and revisit the discrepancy in Re–Os ages for the Neoproterozoic Aralka Formation (central Australia). In addition, we introduce new Re–Os isotope data for the Late Neoproterozoic Doushantuo Formation (South China) that highlights the necessity of a rigorous sampling protocol for depositional age determinations. Improvements in sampling and analytical methodologies have permitted the determination of precise ages (<1%, 2σ) from Late Neoproterozoic to Late Archaean shales. Whole-rock digestion using a Cr VI –H 2 SO 4 solution minimizes the release of detrital Re and Os from shale matrices, and selectively attacks organic matter that hosts hydrogenous Re and Os. The Re–Os system in organic-rich sedimentary rocks appears to be robust during hydrocarbon maturation and up to the onset of lowermost greenschist facies metamorphism, but post-depositional hydrothermal fluid flow can result in scattered Re–Os isotope data. The Re–Os black shale geochronometer should find utility for constraining the age of a diverse range of Precambrian geological phenomena. In addition, the initial 187 Os/ 188 Os composition determined from Re–Os isochron regressions serves as a tracer for the Os isotope composition of Precambrian sea water.

Abstract This review covers global uppermost Neoproterozoic–Cambrian petroleum systems using published information and the results of studies undertaken by the Geological Survey of Western Australia (GSWA) on the Neoproterozoic Officer Basin. Both production and hydrocarbon (HC) shows sourced from, and reservoired in, uppermost Neoproterozoic–Cambrian successions occur worldwide, and these provide ample incentive for continuing exploration for these older petroleum systems. However, the risks of charge volume, timing of generation–migration v. trap formation and preservation of accumulation are significantly higher than in conventional Phanerozoic petroleum systems. Therefore, the location and assessment of preserved HC accumulations in such old petroleum systems presents a significant exploration challenge. Organic-rich metamorphosed Proterozoic successions of SE Greenland, the Ukrainian Krivoy Roy Series, the Canadian Upper Huronian Series and the oil shales of the Russian Onega Basin are known as the world's oldest overmature petroleum source rocks. The oldest live oil has been recovered from the McArthur Basin of Australia ( c . 1.4 Ga; Ga is 10 9 years), followed by the Nonesuch oil of Michigan. Numerous other petroleum shows have been reported from Australia, Canada, China, India, Morocco, Mauritania, Mali, Oman, Pakistan, Venezuela and the USA. These demonstrate that generation and migration of Proterozoic petroleum has occurred worldwide. The Siberian Lena–Tunguska province, the Russian Volga–Ural region and the Middle Eastern south Oman petroleum fields exemplify the productive potential of uppermost Neoproterozoic–Cambrian successions, where petroleum generation, migration and trapping were either late in the geological history (Palaeozoic–Mesozoic, Oman) or where accumulations have been preserved beneath highly effective super-seals (Lena–Tunguska). The total resource potential of the Lena–Tunguska petroleum province is estimated to be 2000 Mbbl (million barrels) oil and 83 Tcf (trillion cubic feet) gas. The equivalent proven and probable reserves derived from Neoproterozoic–Early Cambrian source rocks and trapped in Late Neoproterozoic (Ediacaran), Palaeozoic and Mesozoic reservoirs in Oman are at least 12 bbbl (billion barrels) of oil and an undetermined volume of gas. The recovery of 12 Mcf (million cubic feet) of Precambrian gas from the Ooraminna-1 well in the Amadeus Basin in 1963, together with the occurrence of numerous HC shows within the Australian Centralian Superbasin, triggered the initial exploration for Proterozoic hydrocarbons in Australia. This included exploration in the Neoproterozoic Officer Basin, which is reviewed in this paper as a case study. Minor oil shows and numerous bitumen occurrences have been reported from the 24 petroleum exploration wells drilled in the Officer Basin to date, indicating the existence of a Neoproterozoic petroleum system. However, the potential of the Neoproterozoic petroleum system in the vast underexplored Officer Basin, with its sparse well control, remains unverified, but may be significant, as may that of many other ‘Infracambrian’ basins around the world.

Abstract Despite the existence of proven Neoproterozoic–Early Cambrian (‘Infracambrian’) hydrocarbon plays in many parts of the world, the Neoproterozoic Eon, from 1000 Ma to the base of the Cambrian at 542 Ma, is relatively poorly known from a petroleum perspective. The so-called ‘Peri-Gondwanan Margin’ is one region of the Neoproterozoic world that is exciting particular interest in the search for ‘old’ hydrocarbon plays, mainly due to exploration success in time-equivalent sequences of Oman. The ‘Infracambrian’ succession in North Africa is widely accessible, and is already emerging as a hydrocarbon exploration target with considerable potential and with proven petroleum systems in different areas. The Taoudenni Basin (Mauritania, Mali, Algeria) in western North Africa is an underexplored basin, despite the Abolag-1 well (Texaco 1974) gas discovery. New palynological data have recently provided the first definitive Late Riphean age dates for the stromatolitic limestone reservoir sequence in Abolag-1. The widespread presence of stromatolitic carbonate units of potential reservoir facies in many parts of North Africa has been confirmed by new fieldwork in the Taoudenni Basin, in the Anti-Atlas region of Morocco and in the Al Kufrah Basin of Libya. Similar biostratigraphic age constraints have also been obtained from subsurface sequences of the Cyrenaica Platform bordering the East Sirte Basin of Libya, many of which have been traditionally assigned an ‘unconstrained’ Cambro-Ordovician age on the basis of lithological characteristics. Besides the proven, producing, weathered-granite reservoir in East Sirte Basin, the hydrocarbon potential of Neoproterozoic–Early Cambrian sequences developed in structural troughs bordering the south Cyrenaica Platform is still being evalutated. Neoproterozoic–Early Cambrian organic-rich strata with hydrocarbon source rock potential are widespread along the Peri-Gondwanan Margin. Some of the black shales encountered on the West African Craton may be as old as 1000 Ma and predate the Pan-African orogenic event. The Late Ordovician–Early Silurian systems in North Africa and the Middle East may form a good analogue for post-glacial source rock depositional systems in the Neoproterozoic, where black shale deposition may also have been triggered by post-glacial sea-level rise.

Abstract Proven Infracambrian hydrocarbon plays occur in various parts of the world, including Oman, the former Soviet Union, India, Pakistan and Australia. Organic-rich strata also occur in NW Africa, and gas shows originating from Infracambrian hydrocarbon source rocks are known from well Abolag-1 in the Mauritanian part of the Taoudenni Basin. The distribution of Infracambrian source rocks in North Africa is patchy and deposition commonly occurred in half-graben and pull-apart basins. In these intra-shelf basins, marine, organic-rich shales and limestones were deposited beneath the turbulent wave zone, away from the coarse siliciclastic Pan-African molasse detritus. On the West African Craton (including the Taoudenni Basin) organic-rich horizons were also deposited earlier, in pre- and syn-Pan-African times between 0.5 and 2 Ga (Ga is 10 9 years). The long-lasting sedimentation history in this area contrasts with that of the Pan-African regions, such as Oman, which lies in the Pan-African province of the East African Orogen, where preserved sediments are rarely older than 640 Ma. Infracambrian black phyllites in the Anti-Atlas region of Morocco were deposited on a continental slope of a short-lived ocean lying to the north of the West African Craton. Hydrocarbons generated during Infracambrian times from these deposits, however, have a low preservation potential. Infracambrian organic-rich and/or black-pyritic deposits in North Africa are proven in the Taoudenni Basin, the Anti-Atlas and the Ahnet Basin. Thick carbonate successions exist in the Taoudenni Basin, indicating deposition in areas some distance from contaminating coarse siliciclastic hinterland influx. Infracambrian strata may also occur in the Tindouf Basin. However, their deep burial and consequent early maturation history may be unfavourable for the preservation of Infracambrian-sourced hydrocarbons in this area. Local development of Infracambrian source facies may also occur in the Reggane, Ahnet, Mouydir and Iullemeden basins, as indicated by black shales in wells MKRN-1 and MKRS-1 in the Ahnet Basin. Generally, however, these basins appear to be close to the active Pan-African orogenic belt and, consequently, probably received large quantities of coarse siliciclastic sediment, largely of continental facies, which may have diluted any significant hydrocarbon source potential.

Abstract Infracambrian sediments are widely distributed in Libya, outcropping on the eastern and western margins of Al Kufrah Basin and the eastern margin of Murzuq Basin. The sediments have been penetrated in the Central Cyrenaica Platform, Concession 10, NW Sirte Basin, and Block NC115, NW Murzuq Basin. There are two main subdivisions. The first is metamorphosed due to local volcanism in the Murzuq and Al Kufrah basins. The second is unaltered and has been penetrated in the NW Sirte Basin. It occurs as outcropping limestone on the eastern margin of the Murzuq Basin. These sediments generally show lateral thickness variability, with the thickest section, approximately 991–1067 m, in the Cyrenaica Platform. Individual units show thinning towards the Precambrian basement highs, and both fining-up and coarsening-up successions. Two-dimensional seismic data acquired by the operating companies AGIP and AGOCO in the southern Al Kufrah Basin image strata presumed to be Infracambrian. The Infracambrian sediments were probably deposited as lens-shaped bodies in palaeo-lows (graben, half-graben and troughs) alongside Precambrian basement highs, trending NW–SE in the Cyrenaica platform and NE–SW in the Al Kufrah and Murzuq basins. These sediments show lateral facies changes and their nomenclature differs across the basins. Palynological and palaeontological studies suggest a Late Riphean age.

Abstract Field-based investigation of ‘Infracambrian’ rocks cropping out on the eastern flank of Al Kufrah Basin (area 500 000 km 2 ) reveals a an approximately 500 m-thick clastic succession of massive and cross-bedded sandstones, separated by 60 m-thick mudrock intervals. New zircon age data indicate a maximum age of deposition of approximately 950 Ma; furthermore, the absence of zircons of Pan-African age suggests a minimum depositional age older than the Pan-African Orogeny. Previously unreported folding and spaced cleavage affects these deposits to produce a pronounced NE–SW-striking tectonic grain that is interpreted to result from NW–SE-directed orthogonal compression during the Pan-African Orogeny. These Infracambrian rocks are therefore unlikely to be suitable analogues for weakly deformed strata shown to exist beneath the Cambro-Ordovician strata of the Al Kufrah Basin. Earlier work mapped a series of Infracambrian marble outcrops along strike of the clastic deposits; thin section petrography reveals that some of these are basic igneous rocks metamorphosed to greenschist facies. Interpretation of gravity data over the Al Kufrah Basin shows NE–SW-striking faults, parallel to outcrop structures, and secondary NW–SE faults. The data do not support earlier interpretations of a rhomboidal geometry in the deep subsurface of the basin, which has previously been attributed to strike-slip (pull-apart) processes. This research impacts on earlier suggestions that the Al Kufrah Basin opened as one of a series of en echelon pull-apart basins situated along a 6000 km-long shear zone known as the Transafrican Lineament, stretching from the Nile to the Niger Delta.

Abstract This paper presents an overview of the distribution of the Infracambrian rocks within the Murzuq and Al Kufrah basins obtained by integrating existing data and new outcrop and subsurface data, and discusses the implications for the regional depositional setting and hydrocarbon potential. In the Murzuq Basin the Infracambrian units comprise volcaniclastics, metasediments and fine- to medium-grained sandstones with an average thickness of 61 m, reflecting a proximal, clastic-dominated depositional system. In the Al Kufrah Basin carbonate facies in Jabal Arkanu (eastern margin) indicate that the distal facies may become organic-rich. Interpreted seismic lines reveal Infracambrian graben systems similar to those found elsewhere that provide good hydrocarbon source rocks in petroliferous basins.

Abstract The Taoudenni Basin, North Africa's largest sedimentary basin, is located in western Mauritania, northern Mali and southwestern Algeria. Of the four petroleum wildcat wells drilled to date, the Abolag-1 well, Mauritania, yielded gas shows in Infracambrian (Neoproterozoic) stromatolitic carbonates. We present details of the different plays of the basin from the Chenachène region in Algeria. The Infracambrian is generally composed of three sedimentary packages: a basal sandstone (a unit of the Douik Group), overlain by carbonates (the Hank Group), sandstones and shales (the Dar Echeikh Group). The play is sourced by Infracambrian organic-rich black shales. In neighbouring Mauritania these were penetrated by water wells and shallow boreholes, containing in places >20% TOC. In the Hank Group the best reservoirs are associated with fractured intervals. The Dar Echeikh Group includes several potential reservoir units with porosities of up to 26%. Potential petroleum trap types in the Algerian part of the Taoudenni Basin are associated with folds, the basal Palaeozoic unconformity, and Infracambrian and Triassic–Jurassic half-graben.

Abstract The intra-Vendian (Ediacaran)–intra-Tremadocian succession of the Cadenas Ibéricas in NE Spain is divided into nine sequences. Overall, these are interpreted as second-order sequences. Those that encompass Lower and lower Middle Cambrian carbonates, with identified transgressive systems tract (TST) and highstand systems tract (HST) phases, may constitute elements of composite sequences. The lowermost sequence is of Late Vendian age. In Lower and lower Middle Cambrian units, sequence tops indicate drowning, reflecting extensional tectonics. Rifting effects are traceable up to mid-Mid Cambrian times. The remaining sequences probably represent a sag phase, either accentuating the preceding extensional local basin regime or heralding the Gondwana passive margin stage. Of the southerly Gondwana deposits those of other areas of the Iberian Peninsula and of the Moroccan Anti-Atlas fold belt show similar conditions during the Early Cambrian, that is, an Early Cambrian extensional regime, and, as for the Moroccan fold belt, four sequences imaging TST and HST phases.

Abstract The Proterozoic Sirban Limestone of Jammu in northern India contains an assemblage of Neoproterozoic microflora comparable to other such assemblages from different Proterozoic oil- and gas-bearing carbonate successions in India, Morocco and Siberia. The stromatolitic Sirban Limestone succession is composed of lamina-scale organic-rich source rocks, limestone units with good-quality reservoir characteristics and seal horizons that together constitute the basic physical elements of a petroleum system. A reworked microfloral assemblage of Neoproterozoic age is also recovered from the unconformably overlying Subathu Formation (Eocene) from the area. Some in situ elements of this assemblage, including a few genera, were also recovered from the Sirban Limestone. This reworked assemblage may be related either to upwards migration of hydrocarbons from deeper sediments or, more likely, to the existence of the Sirban Limestone and younger Neoproterozoic formations as a positive area that sourced the microflora to the Eocene Subathu Basin.

Abstract The geological paradox of at least two Neoproterozoic glacial intervals at tropical latitudes intercalated within carbonates remains an unsolved puzzle. Several conceptual models have been proposed to explain these apparent rapid swings between climatic extremes and the associated isotopic changes in sea-water chemistry. In Oman, post-glacial transgressive sedimentary successions represent important hydrocarbon source rocks. Source rock characteristics of Neoproterozoic post-glacial successions in other parts of the world (even if not directly correlatable) are, therefore, of special economic interest. This paper concentrates on the Ghaub Formation diamictite interval in northern Namibia and the major environmental change in the aftermath of the assumed glaciation. The relationship of the post-glacial sediments with the underlying different types of cap carbonate and diamictite successions is discussed, and a model of the succession of events is presented. The palaeotopography, caused mostly by ongoing tectonic activity including uplift on the scale of thousands of metres, strongly influenced the petroleum system created and played an important role for the hydrocarbon prospectivity of this post-glacial succession. Tectonic activity on the shelf of the southern margin of the Congo Craton was repeated, and different sub-basins were created before, during and after the Ghaub glaciation. The newly formed relief was flooded, and the different sub-basins were affected by restricted circulation for quite some time. This general scenario bears many similarities to the late Ordovician–early Silurian petroleum system, also formed during post-glacial sea-level rise.

Abstract The classical definition of ‘Infracambrian’ that refers strictly to sequences of Proterozoic age is not applicable in southwestern Gondwana. In this paper the term ‘Infracambrian’ is used to define the sequences deposited during the Pampean orogenic cycle, which extends until the Cambrian period. A classification of Infracambrian basins is proposed based on location, level of preservation and perceived petroleum potential. Only the eastern basins of the South American plate have potentially significant exploration potential. Two Neoproterozoic petroleum systems have been identified in the eastern basins: a Riphean system, developed on the western margin of the San Francisco Craton, in the San Francisco Basin of Brazil; and a Vendian system, developed on the eastern margin of the Amazonia–Río de la Plata cratons, in the Corumbá Basin of Brazil and Paraguay. The Riphean system is reportedly proven by a well test drilled by Petrobras. An active Vendian petroleum system is proven by the presence of oil seeps within fractured limestones. A Vendian petroleum system is proposed for the Claromecó Basin of Argentina based on the correlation of the Vendian and Riphean sequences.