Abstract This study gives valuable insights into the microstructure and pore space characteristics of 17 compositionally variable Visean shale samples from the Ukrainian Dniepr-Donets Basin (the ‘Rudov Beds’). The representative imaging area varies considerably (from 10 000 to >300 000 µm 2 ) as a function of the mineralogy and diagenetic overprinting. The pores hosted in organic matter (OM) are restricted to secondary solid bitumen. Based on high-resolution maps from broad ion beam scanning electron microscopy combined with organic geochemical and bulk mineralogical data, we propose that the amount of OM-hosted porosity responds to the availability of pore space, enabling the accumulation of an early oil phase, which is then progressively transformed to a porous solid bitumen residue. The type of OM porosity (pendular/interface v. spongy) is reflected in the individual pore size distributions: the spongy pores are usually smaller (<50 nm) than the pendular or OM–mineral interface pores. The OM-hosted porosity coincides with differences in the composition of the extract, with high amounts of extractable OM and saturated/aromatic compound ratios indicative of abundant porous solid bitumen. The average circularity and aspect ratio of the mineral matrix pores correlate with the corresponding values for the OM-hosted pores, which show a preferred bedding-parallel orientation, suggesting that compaction influenced both types of pore.

Abstract Opalinus Clay (OPA) is considered as a potential host rock for the deep geological disposal of radioactive waste. One key parameter in long-term storage prediction is permeability. In this study we investigated microstructural controls on permeability for the different facies of OPA. Permeability and porosity were determined under controlled pressure conditions. In addition, the pore space was investigated by SEM, using high-quality surfaces prepared by broad ion beam (BIB) milling. Water permeability coefficients range from 1.6 × 10 −21 to 5.6 × 10 −20 m 2 ; He-pycnometer porosities range between approximately 21 and 12%. The sample with the highest He porosity (shaly facies) is characterized by the lowest permeability, and vice versa (carbonate-rich sandy facies). This inverse behaviour deviates from the generally reported trend of increasing permeability with increasing porosity, indicating that parameters other than porosity affect permeability. Visible porosities from SEM images revealed that 67–95% of the total porosity resides within pores smaller than the SEM detection limit. Pore sizes follow a power-law distribution, with characteristic power-law exponents ( D ) differing greatly between the facies. The carbonate-rich sandy facies contains a network of much larger pores ( D (shaly) ≈2.4; D (carbonate-rich) c. 2.0), because of the presence of load-supporting sand grains that locally prevent clay compaction, and are responsible for a higher permeability.

Abstract Most of the information on subsurface evaporitic structures comes from 3D seismic data. However, this data only provide limited information about the internal structure of the evaporites, which is known from salt mines and salt diapir outcrops. Brittle intra-salt layers (carbonate, anhydrite, clay) of at least 10 m thickness form good reflectors in evaporites, but the structure and dynamics of such ‘stringers’ in the salt movement are poorly understood. In this study, we investigate the intra-salt Zechstein 3 (Z3) stringer from 3D seismic data in an area offshore the Netherlands. Observations show complex deformation including boudinage, folding and stacking. Reflections from thin and steep stringer parts are strongly reduced, and we present different structural models and tests of these. We compare our observations to structural models from salt mines and analogue/numerical models of intra-salt deformation. A smoothed representation of the upper surface of the stringer fragments follows the shape of Top Salt, but smaller-scale stringer geometries strongly differ from this and imply boudinage. The imaged disharmonic patterns of constrictional folds provide evidence for the complexity of the intra-salt, in agreement with observations in salt mines. This may be explained by interaction of the layered salt rheology, complex three-dimensional salt flow, different phases and styles of basement tectonics and movement of the overburden.