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deformation (1)
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tectonics (1)
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Abstract Recrystallized grains are potentially useful as indicators of palaeostress in naturally deformed rocks, providing that well-calibrated relationships (palaeopiezometers) exist between the recrystallized grain size and stress. Rocks can exhibit microstructures that are heterogeneous, that is, containing recrystallized as well as deformed grains, and showing subgrains within grains that differ in size and character from the grain core to the mantle. Previous studies on palaeopiezometers only rarely took into account such heterogeneous microstructure. We used electron backscattered diffraction (EBSD) to accurately quantify the heterogeneous microstructures in experimentally deformed Carrara marble (flow stress 15–85 MPa, temperature 700–990 °C and natural strain 0.15–0.90). The sizes of bulges, recrystallized grains and deformed grains have been measured. We found that the overall character of the microstructures varies as a function of deformation conditions. In heterogeneous samples showing core-mantle microstructures, the sizes of the bulges and recrystallized grains are independent of strain and show an inverse dependency on stress. The recrystallized grains have been found to nucleate at grain boundary bulges. Our study illustrates that very different microstructures may develop in relation to the complexity of the recrystallization mechanisms. We therefore suggest that piezometers should be calibrated and applied for a single type of overall microstructure.
Abstract We present a selective overview of current issues and outstanding problems in the field of deformation mechanisms, rheology and tectonics. A large part of present-day research activities can be grouped into four broad themes. First, the effect of fluids on deformation is the subject of many field and laboratory studies. Fundamental aspects of grain boundary structure and the diffusive properties of fluid-filled grain contacts are currently being investigated, applying modern techniques of light photomicrography, electrical conductivity measurement and Fourier Transform Infrared (FTIR) microanalysis. Second, the interpretation of microstructures and textures is a topic of continuous attention. An improved understanding of the evolution of recrystallization microstructures, boundary misorientations and crystallographic preferred orientations has resulted from the systematic application of new, quantitative analysis and modelling techniques. Third, investigation of the rheology of crust and mantle minerals remains an essential scientific goal. There is a focus on improving the accuracy of flow laws, in order to extrapolate these to nature. Aspects of strain and phase changes are now being taken into account. Fourth, crust and lithosphere tectonics form a subject of research focused on large-scale problems, where the use of analogue models has been particularly successful. However, there still exists a major lack of understanding regarding the microphysical basis of crust- and lithosphere-scale localization of deformation.
Abstract Dead weight uniaxial compaction creep experiments were carried out on fine-grained, super-pure calcite (<74 μm) at room temperature and applied effective stresses of 1–4 MPa. All samples were pre-compacted dry at a stress of 8 MPa, for 30 minutes, to obtain a well-controlled initial porosity. The samples were then wet-compacted under ‘drained’ conditions with pre-saturated solution as pore fluid. Control experiments, which were done either dry or with chemically inert pore fluid, showed negligible compaction. However, samples tested with saturated solution as pore fluid showed easily measurable compaction creep. The compaction strain rate decreased with increasing strain and increasing grain size, and increased with increasing applied stress. Addition of Mg 2+ ions to the saturated solution dramatically inhibited compaction. From the literature, Mg 2+ ions are known to inhibit calcite precipitation. By comparison with a theoretical model for intergranular pressure solution in calcite, the observed mechanical behaviour and the way that compaction responded to the pore fluid chemistry suggest that, under our experimental condition, intergranular pressure solution is the mechanism of the deformation and that precipitation is likely to be the rate-limiting step.
Numerical modelling of pressure solution in sandstone, rate-limiting processes and the effect of clays
Abstract Pressure solution is an efficient mechanism for ductile deformation and local mass transport in the upper crust. In this paper we model pressure solution as a mechanism involving four steps: (1) dissolution at the grain contacts; (2) diffusion of solutes through fluid films at the contact between two grains; (3) transport of solutes by diffusion through the pore fluid into other adjacent open pores; and (4) precipitation on the surface of grains at their contact with the pore fluid. In this study we constrain under which conditions pressure solution is limited by one of the four processes: dissolution; contact diffusion; precipitation; and global diffusion. From our model of pressure solution, based on thermodynamic relationships we derive three dimensionless numbers which represent the competetion between the four mentioned processes. With these numbers we can define the crossover from a situation where one process acts as the limiting process to a new situation controlled by another process. We also see how the different rate-limiting processes influence the amount of mass transported during the compaction process. In addition we study the effect of clays, as it has been suggested that these minerals speed up the rate of pressure solution. We propose two models, a chemical related and a mechanical model for how the clay particles may affect the dissolution process of quartz.
Abstract It is widely claimed that the presence of phyllosilicates in sandstones increases intergranular pressure solution (IPS) rates in these rocks. However, this has not been experimentally confirmed. This study reports the results of isostatic hot-pressing compaction experiments at a temperature of 500°C and an effective pressure of 100 MPa on mixtures of quartz and muscovite. Previous work has shown that under these conditions dissolution is rate controlling in pure quartz. No acceleration of compaction rates of quartz by the addition of muscovite was observed. Instead, a modest decrease in compaction rates was observed (factor 3–10), which we infer was due to a decrease in IPS rate. The effect of muscovite in slowing IPS may be due to the influence of dissolved aluminum (Al 3+ ) dominating over any accelerating effects of alkali-metal cations. From the geochemical literature, Al 3+ in solution is expected to decrease the solubility, dissolution rates and precipitation rates of quartz. However, the effect of the addition of muscovite on IPS rates in quartz when controlled by diffusion or precipitation may be different. Experiments should be conducted on quartz sand under conditions where diffusion or precipitation is rate controlling to investigate these possible effects.
In situ experimental study of roughness development at a stressed solid/fluid interface
Abstract Theory and experiments have demonstrated that the initially flat surface of an elastically strained solid is morphologically unstable. The elastic strain energy of a rough, corrugated surface is lower than that of a flat one. Hence, stress forces the surface into a rough structure, but the associated increase in surface energy counteracts this roughening. In this way an equilibrium surface roughness consisting of μm-scale grooves and ridges can develop if the solid is transported, e.g. by diffusion through an aqueous solution, from sites of high stress to sites of low stress. We report in situ experimental observations of the surface of elastically strained potassium (K-) alum single crystals held in K-alum solution. The observations confirm earlier reports of the development of stress-induced μm-scale grooves on the surface of this material. The in situ observations show, however, that the stress-induced surface morphology is not a static, but a dynamic structure. The grooves are mobile, and may for example propagate or increase or decrease in length. They may move upwards, downwards, or remain where they are. Others rotate and undulate. It is suggested that if stress is high enough, grain boundaries in (wet) rocks could posses a similar structure of channels, continuously changing position and orientation, in line with the so-called ‘dynamically stable’ island-channel grain boundary structure that is essential to several pressure solution models.
Fluid-assisted large strains in a crustal-scale décollement (Hercynian Belt of South Brittany, France)
Abstract Crustal deformations often occur along gently-dipping shear zones, where the scale of fluid transfers and the coupling between deformations and fluid availability are important questions. We present a structural and geochemical study of felsic rocks deformed at about 350–400°C within a crustal-scale décollement zone from the Hercynian Belt of South Brittany. At regional scale, deformations resulted in large distributed strains accumulated by dissolution-crystallization of quartz and feldspars. Mass transfers produced veins growing parallel to the foliation. Veins were major precipitation zones, while adjacent rocks were the main zones of dissolution. Deformation patterns, vein mineralogy, and oxygen isotope data show that both the amount of fluids and the scale of fluid flow were limited, and that the dominant transfer mechanism was diffusion. Results suggest that the deformation zone has acted as a trap for early fluids rather than as a syn-kinematic fluid channel.
Abstract Several recent studies have suggested that antitaxial fibrous veins may form without fracturing, and not by the commonly invoked crack-seal mechanism. It has also been suggested that such veins would derive their nutrients locally by diffusional transport. This hypothesis was tested on carbonaceous shale-hosted antitaxial fibrous calcite veins from Oppaminda Creek in the northern Flinders Ranges, South Australia. Apart from their fibrous texture, these veins lack the classical features of crack-seal veins, such as wallrock-parallel inclusion bands. Diffusional transport of locally derived calcite cannot explain all major and trace element data of the veins and their adjacent wallrock and indicate that part of the calcite was transported over distances of at least >decimetres, probably ≫100m. Sr isotopic fingerprinting shows that an external fluid that carried radiogenic Sr must have percolated through the system. Fluid flow was pervasive as there is no evidence that this fluid preferentially percolated through the veins. Our data support the view that antitaxial fibrous veins of the type found at Oppaminda Creek grew in the absence of fractures, but show that such veins do not necessarily indicate local diffusional transport. Our data confirm a recently postulated basin-wide fluid flow event around 586 Ma that is probably related to copper mineralization in the area.
Effects of stress on the anisotropic development of permeability during mechanical compaction of porous sandstones
Abstract To investigate the influence of stress on permeability anisotropy during mechanical compaction, a series of triaxial compression experiments with a new loading configuration called hybrid compression were conducted on three porous sandstones. The effective mean and differential stresses in hybrid compression tests were identical to those in conventional triaxial extension tests. Permeability was measured along the axial direction in both hybrid compression and conventional extension tests, which corresponds to flow along the maximum principal stress direction in the former case and the minimum principal stress direction in the latter case. Since their loading paths coincide, the comparison of permeability values from the two types of tests provides quantitative estimates of the development of permeability anisotropy as a function of effective mean and differential stresses. Our data show that the permeability evolution is primarily controlled by stress. Before the onset of shear-enhanced compaction C * , permeability and porosity reduction are solely controlled by the effective mean stress, with negligible stress-induced anisotropy. With the onset of shear-enhanced compaction and initiation of cataclastic flow, the deviatoric stress induces enhanced permeability and porosity reduction. The permeability tensor may show significant anisotropy. Our data indicate that the maximum principal component of permeability tensor k 1 is parallel to the maximum principal stress σ 1 , and the minimum principal component k 3 is parallel to the minimum principal stress σ 3 . During the initiation and development of shear-enhanced compaction, k 1 can exceed k 3 by as much as two orders of magnitude. With the progressive development of cataclastic flow, changes of permeability and porosity become gradual again, and the stress-induced permeability anisotropy diminishes as k 1 and k 3 gradually converge. Our data imply that permeability can be highly anisotropic in tectonic settings undergoing cataclastic flow, inducing the fluid to flow preferentially along conduits subparallel to the maximum compression direction. However, this development of permeability anisotropy is transient in nature, becoming negligible with an accumulation of strain of about 10%. The anisotropic development of permeability in a lithified rock is dominantly controlled by microcracking and pore collapse. This is fundamentally different from the mechanisms active in unconsolidated materials such as sediments and fault gouges, in which the permeability evolution is primarily controlled by the development of fabric and shear localization via the accumulation of shear strain.
Abstract This review discusses the attempts that have been made by geologists to numerically simulate the evolution of microstructures in rocks. The strengths and weaknesses of the differing techniques are compared and equivalent materials science results are included. In particular we focus on the application of techniques that have been used to predict texture development, grain boundary geometries, deformation in one and two-phase systems and crystal growth.
Abstract The influence of the dominance of different processes on the microstructural development of a quartzite was investigated using the numerical model ‘ELLE’. Dynamic recrystallization of a polycrystalline aggregate was simulated by the concurrent operation of viscous deformation, lattice rotation, subgrain formation, rotational recrystallization, nucleation of new grains from strongly strained grains and recovery. The different observed microstructural characteristics depend on the relative rates at which grain boundary migration, subgrain formation, recrystallization by rotation and nucleation affect the microstructure. Observed sizes of recrystallized grains are significantly influenced by these different relative rates of processes. These rates are determined by parameters that mainly depend on temperature, fluid absence or presence, shear stress and strain rate. Therefore, the specific conditions at which deformation took place have to be taken into account if recrystallized grain sizes are used for palaeopiezometry. Comparison and combination of our results with experimental data and observations in natural examples provide the possibility of interpreting microstructures quantitatively in terms of temperature and shear strain rate.
Dynamic recrystallization of quartz: Correlation between natural and experimental conditions
Abstract Quartz veins in the Eastern Tonale mylonite zone (Italian Alps) were deformed in strike-slip shear. Due to the synkinematic emplacement of the Adamello Pluton, a temperature gradient between 280°C and 700°C was effected across this fault zone. The resulting dynamic recrystallization microstructures are characteristic of bulging recrystallization, subgrain rotation recrystallization and grain boundary migration recrystallization. The transitions in recrystallization mechanisms are marked by discrete changes of grain size dependence on temperature. Differential stresses are calculated from the recrystallized grain size data using paleopiezometric relationships. Deformation temperatures are obtained from metamorphic reactions in the deformed host rock. Flow stresses and deformation temperatures are used to determine the strain rate of the Tonale mylonites through integration with several published flow laws yielding an average rate of approximately 10 −14 s −1 to 10 −12 s −1 . The deformation conditions of the natural fault rocks are compared and correlated with three experimental dislocation creep regimes of quartz of Hirth & Tullis. Linking the microstructures of the naturally and experimentally deformed quartz rocks, a recrystallization mechanism map is presented. This map permits the derivation of temperature and strain rate for mylonitic fault rocks once the recrystallization mechanism is known.
Abstract Quartzite samples were experimentally deformed with partial to complete dynamic recrystallization by axial compression (strain magnitude of 0.8 to 1.4) and by general shear (strain magnitude of 1.3 to 2.8) in each of the three dislocation creep regimes, and subsequently annealed with complete static recrystallization at the deformation temperature for 120 hours. The c -axis crystallographic preferred orientation (CPO), 3D grain size distribution, grain boundary surface shape, and misorientation density were measured before and after annealing. The effect of annealing on the CPO was minor, but the microstructure was greatly changed. All of the annealed samples were completely recrystallized. The recrystallized grain size increased by a factor of 2 to 5, and was greatest for samples deformed at lowest temperature. The grain boundary lobateness (PARIS factor) and misorientation density were reduced significantly. The CPOs for all the deformed samples were relatively unchanged by annealing, although the strengths are somewhat decreased; for sheared samples the asymmetry was preserved. The results suggest microstructural criteria for recognizing the occurrence of static annealing and for estimating the dynamically recrystallized grain size relevant for paleopiezometry from annealed samples.
Abstract Neutron texture analyses of quartz-bearing and quartz-free amphibolite mylonites from the Windy Pass thrust, Cascades Crystalline Core (Washington/USA) reveal pronounced textures of plagioclase and clino-amphiboles (hornblende, cummingtonite) but no preferred orientation of quartz. A reliable strategy for amphibolite fabric analysis is presented by a systematic analytical approach to the experimental diffraction data processing. Clino-amphiboles show transitional textures between ideal single crystal orientations and axial symmetric great circle distributions. Plagioclase reveals a -axes distributions scattering along a great circle approximating the foliation plane as well as a -axes maxima close to the macroscopic lineation. Correlation of the textures with grain shape anisotropies of horn-blende and plagioclase and comparison with data from the literature suggest that the texture variations are due to different strain regimes rather than due to different crystallographic reorientation mechanisms. The kinematic directions deduced from the microfabric correlate well with the regional tectonic interpretations. In contrast, individual deformation paths are not yet established for the different tectonic units, as the significance of the separating Windy Pass thrust requires further structural analysis and fabric studies.
Abstract X-ray and neutron diffraction techniques have been applied to quantitative texture analysis of a glaucophanite from the Sesia-Lanzo Zone (Western Italian Alps), naturally deformed under eclogite facies conditions. The comparison has been carried out in order to reveal the limits and problems of texture analysis related to strongly deformed polymineralic. Different methods of measuring and computing the orientation distribution function from diffraction data have been tested, in particular X-rays, direct peak integration, and neutron diffraction using Rietveld-texture analysis. Due to grain-size problems and heterogeneity of individual amphibole minerals, neutron radiation is shown to be the best probe for characterizing the whole rock: being more penetrative than conventional X-rays, a larger volume of the mineral aggregate is sampled, giving better statistics. However, results obtained by summing the corresponding individual spectra of at least three X-ray diffraction experiments on parallel slabs of the same specimen also give statistically valid, semiquantitative results that reproduce the overall textures. The quantitative texture analysis shows the strong texture of the two generations of amphiboles (AmpI and AmpII), which are mainly characterized by [001]*-directions at an angle of about 10° to the mineral lineation and by ( hk0 ) planes describing girdles around the lineation. The texture is comparable to those described in the literature for amphibole deformed under different temperature and pressure conditions, and the pronounced asymmetry of the [001]* directions with respect to the mineral lineation is consistent with a non-coaxial component that occurs during the deformation.
Stress and deformation in subduction zones: Insight from the record of exhumed metamorphic rocks
Abstract High pressure (HP) and ultrahigh (UHP) metamorphic rocks are exhumed from subduction zones at high rates on the order of plate velocity (cm/year). Their structural and microstructural record provides insight into conditions and physical state along the plate interface in subduction zones to depths of >100 km. Amazingly, many identified (U)HP metamorphic rocks appear not to be significantly deformed at (U)HP conditions, despite their history within a high strain rate mega-shearzone. Other (U)HP metamorphic rocks seem to be deformed exclusively by dissolution-precipitation creep. Indications of deformation by dislocation creep are lacking, apart from omphacite in some eclogites. Available flow laws for dislocation creep (extrapolated to low natural strain rates, which is equivalent to no deformation on the time scales of subduction and exhumation, i.e., 1 to 10 Ma) pose an upper bound to the magnitude of stress as a function of temperature along the trajectory followed by the rock. Although the record of exhumed (U)HP metamorphic rocks may only be representative of specific types or evolutionary stages of subduction zones, for such cases it implies: (1) strongly localized deformation; (2) predominance of dissolution-precipitation creep and fluid-assisted granular flow in the shear zones, suggesting Newtonian behaviour; (3) low magnitude of differential stress; which (4) is on the order of the stress drop inferred for earthquakes; and (5) negligible shear heating. These findings are easily reconciled with exhumation by forced flow in a low viscosity subduction channel prior to collision, implying effective decoupling between the plates.
Non-linear feedback loops in the rheology of cooling-crystallizing felsic magma and heating-melting felsic rock
Abstract At least six major parameters control the rheology of partially molten systems: melt content, rate of melt production, reaction to strain of the solid component, reaction to strain of the molten component, temperature and chemical composition of the source rocks. We examine their interactions to understand the rheology of partly molten rocks and partly crystallized magmas. In particular, this paper focuses on the rheology in the transitional domains between two pairs of thresholds that bracket a transitional regime between solid state and fluid behaviour during melting and crystallization, respectively. We review related information and point out non-linear effects that develop during heating of melting rocks and cooling of crystallizing magmas. Owing to the non-linear interactions, positive or negative feedback loops accelerate or damp the system. Melt in migmatite experiences shear-softening which, along with strain partitioning, facilitates melt segregation. Conversely, the increasing number of rigid crystals during cooling increases the suspension viscosity (shear hardening), which soon inhibits magma movement. These effects reinforce the asymmetry between solid-to-melt and melt-to-solid transitions. They severely contradict the concept of one rheological critical melt percentage valid for both melting and crystallization transitions. Fabric acquisition competes with nucleation and crystal growth, thus leading to hysteresis of the stress-strain rate curves. Implications for field observations include horizontal magma segregation, magma extraction and successive magma intrusions.
Abstract The power-law creep equation, ε̇ ∞ σ n exp(− Q/RT ), is commonly used to relate strain rate, ε̇ , stress, σ , and temperature, T , for thermally activated dislocation creep in rocks. When triaxial deformation experiments on marble and limestone samples are performed at temperatures of 400–1050°C, to strains <0.2, and with strain rates between 10 −3 and 10 −7 s −1 , the variations in strength among different rocks at nominally identical conditions are much larger than the experimental uncertainty. During dislocation creep, the strengths of various limestones and marbles decrease with increasing grain size, similar to the Hall-Petch effect in metals. The stress sensitivity of strain rate, n ′ = ∂ ln ε̇ / ∂ ln σ , and the temperature sensitivity of strain rate, Q ′ = − R ∂ ln ε̇ / ∂ (1/ T ), differ greatly for the various calcite aggregates. There is a systematic dependence of n ′ and Q ′ on stress, grain size, and perhaps, temperature, and there is no interval in stress where n ′ is constant. Thus, the steady-state power-law equation is an inadequate description of dislocation creep in calcite rocks. To improve the constitutive law, it may be necessary to include at least one additional state variable that scales with grain size.
Abstract Field studies of calcite mylonites often document microstructures produced by dislocation creep. In contrast, flow laws derived from experiments predict that calcite rocks should deform mostly by diffusion creep during tectonic processes. To investigate this apparent discrepancy, we compare stresses estimated by microstructural piezometers to those obtained by extrapolation of experimentally derived flow laws. Considering shear zones from different geological settings, a clear trend is observed of increasing recrystallized grain size with increasing temperature. However, there is a large spread in grain size and associated stress. Because separate flow laws have been defined for various different marbles and limestones, the strengths predicted for a given set of conditions differ significantly. The stress estimates based on the piezometers and strength extrapolated from the various experimentally derived dislocation creep flow laws agree qualitatively, but no single flow law predicts all the palaeostress estimates. Even if experimental data are disregarded, the field observations are not consistent with a hypothetical law for Coble creep; they are consistent with a power law for dislocation creep, but only if the material constants are different from those currently determined in laboratory experiments.