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This chapter examines the use of industrial clay minerals as nanomaterials. In the first part, clay minerals are introduced and a survey is given of those properties which are relevant for clay-polymer nanocomposites (CPN). These properties are: morphology of the clay-mineral particles, sizes and shapes of the layers, cation exchange, and hydro-philic and hydrophobic properties. Then, the methods of CPN preparation are reviewed briefly, followed by the factors which influence the properties of CPN. Special attention is given to clay-mineral-based bionanocomposites and functional clay-minerals films. The latter can be prepared by spin coating, layer-by-layer assemblage and the Lang-muir-Blodgett technique. A broad range of properties can be introduced in films prepared with appropriate molecules such as polymers, chiral molecules, molecules with non-linear optical properties and magnetic molecules. The area of CPN is broad and open for fundamental and applied research.

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