Solid Solutions in Silicate and Oxide Systems

The EMU book series or notes, as they are called, were introduced to provide university teachers with up-to-date reviews in important, rapidly evolving areas of mineralogy, petrology and geochemistry. They are also meant to introduce scientists into special and often interdisciplinary fields of research. In this regard, a volume on solid solutions is current and sorely needed. The solid Earth, as well as many meteorites and the other solid planets, consists for the most part of mineral solid solutions. Research on solid solutions is extremely broad encompassing work in physics and chemistry, metallurgy, materials science and, last but not least, mineralogy and petrology. Hence, because the theme is so strongly interdisciplinary in nature, the workshop was organised to include solid state physicists, physical chemists, crystallographers, mineralogists and petrologists. The various chapters reflect some of this diversity and show what mineralogy has become. Experimental investigations in mineralogy now routinely include different types of spectroscopies along with more traditional phase equilibrium, X-ray diffraction, calorimetry, and TEM methods. There have also been new and impressive developments in theory and computation. Many computational approaches relating to the study of solid solutions, for example, the Cluster Variation Method or Monte Carlo simulations, have been brought in from materials science, chemistry and physics. It can be concluded that the traditional or historical, and perhaps artificial, boundaries between the various disciplines are disappearing. Many current research efforts in mineralogy are similar to those in chemistry, materials science and physics.
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Table of Contents
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Introduction
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Solid solutions: Background, history and scientific perspectiveAuthor(s)Charles A. GeigerCharles A. GeigerInstitute of Geological Sciences, Christian Albrechts University at Kiel,
Olshausenstr. 40, D-24098 Kiel, Germany;
e-mail: chg@min.uni-kiel.deSearch for other works by this author on:
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Thermodynamics
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Dependence of thermodynamic properties on atomic masses and bonding in solidsAuthor(s)Göran GrimvallGöran GrimvallTheoretical physics, Department of Physics, Royal Institute of Technology,
SE-100 44 Stockholm, Sweden;
e-mail: grimvall@theophys.kth.seSearch for other works by this author on: -
Thermodynamic modelling of solid solutionsAuthor(s)Jibamitra GangulyJibamitra GangulyDepartment of Geosciences, University of Arizona,
Tucson, AZ 85721, USA;
e-mail: ganguly@geo.arizona.eduSearch for other works by this author on: -
Thermodynamic mixing properties of binary oxide and silicate solid solutions determined by direct measurements: The role of strainAuthor(s)Charles A. GeigerCharles A. GeigerInstitute of Geological Sciences,
Christian Albrechts University at Kiel,
Olshausenstr. 40, D-24098 Kiel, Germany;
e-mail: chg@min.uni-kiel.deSearch for other works by this author on: -
Activity–composition relationships and pressure–temperature determinations in metamorphic rocksAuthor(s)Thomas M. WillThomas M. WillMineralogisches Institut der Universität Würzburg,
Am Hubland, 97074 Würzburg, Germany;
e-mail: thomas.will@mail.uni-wuerzburg.deSearch for other works by this author on:
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Crystal chemistry and structure
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The phenomenological theory of solid solutionsAuthor(s)Vadim S. UrusovVadim S. UrusovDepartment of Crystallography and Crystal Chemistry,
Moscow University, 119899 Moscow, Russia;
e-mail: urusov@geol.msu.ruSearch for other works by this author on: -
The influence of elastic strain heterogeneities in silicate solid solutionsAuthor(s)Michael A. Carpenter;Michael A. Carpenter1Department of Earth Sciences, University of Cambridge,
Downing Street, Cambridge CB2 3EQ, U.K.Search for other works by this author on:Tiziana Boffa BallaranTiziana Boffa Ballaran2Bayerisches Geoinstitut, Universität Bayreuth, D-95440 Bayreuth, Germany;
e-mail: mc43@esc.cam.ac.ukSearch for other works by this author on: -
The diffraction experiment in the study of solid solutions: Long-range propertiesAuthor(s)Roberta ObertiRoberta ObertiCNR-Centro di Studio per la Cristallochimica e la Cristallografia,
Via Ferrata 1, I-27100 Pavia, Italy:
e-mail: oberti@crystal. unipv.itSearch for other works by this author on:
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Computational studies
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Principles of computer simulationAuthor(s)Volker HeineVolker HeineSearch for other works by this author on:
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Computer simulations of solid solutionsAuthor(s)Martin T. DoveMartin T. DoveDepartment of Earth Sciences, University of Cambridge,
Downing Street, Cambridge CB2 3EQ, U.K.;
e-mail: martin@esc.cam.ac.ukSearch for other works by this author on: -
Trace element incorporation in minerals and meltsAuthor(s)Neil L. Allan;Neil L. Allan1School of Chemistry, University of Bristol, Cantock’s Close, Bristol BS8 1TS, U.K.Search for other works by this author on:Jon D. Blundy;Jon D. Blundy2CETSEI, Department of Earth Sciences, University of Bristol, Bristol BS8 1RJ, U.K.Search for other works by this author on:John A. Purton;John A. Purton3CLRC, Daresbury Laboratory, Warrington, Cheshire WA4 4AD, U.K.Search for other works by this author on:Mikhail Yu. Lavrentiev;Mikhail Yu. Lavrentiev1School of Chemistry, University of Bristol, Cantock’s Close, Bristol BS8 1TS, U.K.Search for other works by this author on:Bernard J. WoodBernard J. Wood2CETSEI, Department of Earth Sciences, University of Bristol, Bristol BS8 1RJ, U.K.Search for other works by this author on:
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Configurational entropy of binary silicate solid solutionsAuthor(s)Victor L. VinogradVictor L. VinogradInstitute of Mineralogy, Münster University,
D-48149, Münster, Germany;
e-mail: vinogra@uni-muenster.deSearch for other works by this author on:
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Microscopic properties and glasses
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Magnetic ordering in solid solutionsAuthor(s)Richard J. Harrison;Richard J. HarrisonInstitute of Mineralogy, Münster University,
D-48149, Münster, Germany;Search for other works by this author on:Udo BeckerUdo BeckerInstitute of Mineralogy, Münster University,
D-48149, Münster, Germany;Search for other works by this author on: -
Transmission electron microscopy, defects, and exsolution in rock-forming mineralsAuthor(s)David R. VeblenDavid R. VeblenDepartment of Earth and Planetary Sciences, The Johns Hopkins University,
Baltimore, Maryland 21218 U.S.A.;
e-mail: dveblen@jhu.eduSearch for other works by this author on: -
Glasses and the glass transitionAuthor(s)Pascal RichetPascal RichetMaterials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama, 226-8503 Japan Permanent address: Laboratoire de Physique des Géomatériaux, Institut de Physique du Globe; 4, place Jussieu, 75252 Paris cedex 05, France; e-mail: richet@ipgp.jussieu.frSearch for other works by this author on:
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