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Book Chapter

Discovery of post-perovskite phase transition and implications for the nature of the D″ layer of the mantle

By
Kei Hirose
Kei Hirose
1
Department of Earth and Planetary Sciences, Tokyo Institute of Technology, Meguro, Tokyo 152-8551, Japan
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Katsuyuki Kawamura
Katsuyuki Kawamura
1
Department of Earth and Planetary Sciences, Tokyo Institute of Technology, Meguro, Tokyo 152-8551, Japan
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Published:
January 01, 2007

MgSiO3 perovskite is a principal mineral in the upper part of the lower mantle, but its stability and possible phase transition at greater depths have long been uncertain Recently, a new high-pressure MgSiO3 polymorph called “post-perovskite” was discovered above 125 GPa and 2500 K on the basis of X-ray diffraction measurements in a laser-heated diamond anvil cell (LH-DAC). Crystal structure of post-perovskite was first determined to be orthorhombic (space group: Cmcm) by molecular dynamics (MD) calculations. The first-principles theoretical calculations also confirmed the stability of this new phase. These results suggest that MgSiO3-rich post-perovskite is a predominant mineral below 2500–2700 km depth near the base of the mantle. The D″ layer has long been the most enigmatic region in Earth's interior. The post-perovskite phase can account for the large seismic anomalies observed in the D″ region, such as D″ discontinuity, polarization anisotropy, and anticorrelation between S-wave and bulk sound velocities. The long-term enigma may be explained with this newly discovered crystal.

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GSA Special Papers

Advances in High-Pressure Mineralogy

Eiji Ohtani
Eiji Ohtani
Institute of Mineralogy, Petrology, and Economic Geology, Faculty of Science, Tohoku University, Sendai 980-8578, Japan
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Geological Society of America
Volume
421
ISBN print:
9780813724218
Publication date:
January 01, 2007

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