Skip to Main Content
Book Chapter

Experimental phase equilibrium studies of garnet-bearing I-type volcanics and high-level intrusives from Northland, New Zealand

By
T. H. Green
T. H. Green
Search for other works by this author on:
Published:
January 01, 1992

Rare garnet phenocrysts and garnet-bearing xenoliths occur in high-silica, metaluminous to peraluminous andesites and dacites (and their high-level intrusive quartz diorite equivalents) from a Miocene calc-alkaline province in Northland, New Zealand. These garnets are among the most Ca-rich (17–28 mol% grossular) garnets of igneous origin so far recorded in calc-alkaline suite rocks. Associated minerals are dominant hornblende and plagioclase and minor augite, occurring as phenocrysts in xenoliths and as inclusions in the garnet. This mineralogy points to the I-type character of the garnet-bearing host magma compositions, and contrasts this garnet occurrence with the more frequently recorded grossular-poor (3–10 mol%) garnets with hypersthene, plagioclase, biotite and cordierite, found in S-type volcanic and intrusive host rocks.

Detailed experimental work on a glass prepared from one of the garnet-bearing dacites closely constrains the conditions under which the natural phenocryst and xenolith mineral assemblages formed. This work was conducted over a pressure-temperature range of 8–20 kbar, 800–1050°C with 3–10 wt% of added H2O, defining overall phase relationships for these conditions. Importantly, amphibole only appears at temperatures of 900°C or less and clinopyroxene at >900°C (with 3wt% H2O). Orthopyroxene occurs with garnet at lower pressure (∼15 kbar with 3wt% H2O; ∼< 10 kbar with 5 wt% H2O). Absence of orthopyroxene from the natural garnet-bearing assemblages indicates pressures above these limits during crystallisation. Plagioclase is markedly suppressed (with respect to temperature) with increasing H2O content, and for pressures of 10–15 kbar, the maximum H2O content possible in the magma with retention of clinopyroxene and plagioclase together (as evident in xenoliths) is 5–6 wt%. Finally, the lack of quartz in any of the xenoliths suggests magma H2O content higher than 3% (where quartz appears with amphibole at 900°C), since the quartz liquidus temperature decreases with increasing H2O content, and with decreasing pressure. In experiments with 5 wt% H2O, a quartz-free field of crystallisation of garnet–clinopyroxene–amphibole–plagioclase occurs between 10 and 15 kbar and temperatures between 850 and 900°C. In addition, detailed experimentally-determined garnet compositional trends, together with ferromagnesian mineral compositional data for specific experiments with 5wt% H2O added and run at 10–13 kbar and ∼900°C, suggest that the natural assemblages formed at these conditions. This implies that the parental dacitic magma must have been derived at mantle depths (the Northland crust is ∼25 km thick), and any basaltic or basaltic andesite precursor must have contained ∼2–3 wt% H2O.

The unique nature of the Northland volcanics and high-level intrusives, preserving evidence of relatively grossular-rich garnet fractionation in the high-pressure crystallisation history of an originally mantle-derived magma, is attributed to a combination of unusually hydrous conditions in the source region, complex tectonic history involving obduction and subduction, possible incorporation of crustal slivers in a mantle-crust interaction zone, and relatively thin (∼25 km) crust.

You do not currently have access to this article.
Don't already have an account? Register

Figures & Tables

Contents

GSA Special Papers

The Second Hutton Symposium on the Origin of Granites and Related Rocks

P. E. Brown
P. E. Brown
Search for other works by this author on:
B. W. Chappell
B. W. Chappell
Search for other works by this author on:
Geological Society of America
Volume
272
ISBN print:
9780813722726
Publication date:
January 01, 1992

References

Related

A comprehensive resource of eBooks for researchers in the Earth Sciences

Related Articles
Related Book Content
Close Modal
This Feature Is Available To Subscribers Only

Sign In or Create an Account

Close Modal
Close Modal