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Analysis of 30 individual pumice blocks, together with bulk samples from the ash-flow member of the Los Chocoyos Ash within the Quezaltenango Valley, Guatemala, demonstrates that prior to its eruption, its associated magma-chamber was zoned. Eruption of a high-K (K2O/Na2O > 1), crystal-poor, biotite-bearing rhyolite with crystal equilibration temperatures of less than 800 °C produced the widespread H-tephra member and the initial phases of the ash-flow member. As the ash-flow eruption continued, a more-heterogeneous, low-K, crystal-rich, cummingtonite- and hornblende-bearing rhyolite became predominant; its phenocrysts had equilibrated at temperatures of about 950 °C. The water content of...

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