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Book Chapter

TiO2–SiO2–PDMS nanocomposites with self-cleaning properties for stone protection and consolidation

By
Chrysi Kapridaki
Chrysi Kapridaki
Technical University of Crete, School of Architectural Engineering, Chania, Greece
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Noni-Pagona Maravelaki
Noni-Pagona Maravelaki
Technical University of Crete, School of Architectural Engineering, Chania, Greece
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Published:
January 01, 2016

Abstract

This study deals with the design of two hydrophobic hybrid SiO2–TiO2 materials and their application in the field of monument conservation. The nanocomposite consolidants were based on the modification of tetraethoxysilane (TEOS) with the incorporation of both TiO2 nanoparticles and hydroxyl-terminated polydimethylsiloxane (PDMS). The TiO2 nanoparticles have been prepared from the hydrolysis of titanium tetraisopropoxide (TTIP) in the presence of oxalic acid as a catalyst. The physico-chemical properties of the designed hydrophobic nanocrystalline SiO2–TiO2–PDMS composites have been extensively studied before their application as consolidants on a limestone. Overall, the effectiveness of the nanocomposites was evaluated by the comparative characterization of untreated and treated stone specimens. The results of both capillary water absorption and contact angle measurements point out that the TiO2–SiO2–PDMS nanocomposites functioned as hydrophobic coatings. Furthermore, the results obtained from microdrilling resistance and Fourier Transform Infrared spectroscopy (FTIR) revealed a penetration depth of the nanocomposites within the stone of c. 15 mm. The innovation of these syntheses pertains to the application of hydrophobic semi-transparent and transparent nanocomposites with self-cleaning and strengthening properties, without altering the colour of the stone surface and the water vapour permeability.

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Contents

Geological Society, London, Special Publications

Sustainable Use of Traditional Geomaterials in Construction Practice

R. Přikryl
R. Přikryl
Charles University in Prague, Czech Republic
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Á. Török
Á. Török
Budapest University of Technology and Economics, Hungary
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M. Gomez-Heras
M. Gomez-Heras
Institute of Geosciences (CSIC, UCM), Spain
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K. Miskovsky
K. Miskovsky
Envix Nord AB, Sweden
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M. Theodoridou
M. Theodoridou
University of Cyprus, Cyprus
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Geological Society of London
Volume
416
ISBN electronic:
9781862397187
Publication date:
January 01, 2016

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