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Book Chapter

Using Paleosols to Understand Paleo-Carbon Burial

By
Nathan D. Sheldon
Nathan D. Sheldon
Department of Earth and Environmental Sciences, 1100 N. University Avenue, University of Michigan, Ann Arbor, Michigan 48109, USA nsheldon@umich.edu
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Neil J. Tabor
Neil J. Tabor
Huffington Department of Earth Sciences, P O Box 750395, Southern Methodist University, Dallas, Texas 75275, USA
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Published:
January 01, 2013

Abstract

It has long been understood that the primary control on atmospheric carbon dioxide levels over geologic time (106−107 years) is silicate weathering. Schematically, this relationship is given by the “Urey Equation,” such as CaSiO3 + CO2 = CaCO3 + SiO2, where the equation represents weathering going from left to right and metamorphism going from right to left. The logic of the Urey Equation can be inverted to look instead at the consumption (and therefore burial) of carbon due to weathering because, for example, it requires 2 moles of CO2 from all sources (diffusion, rainfall, in situ productivity) to weather 1 mole of silicate Ca2+. Thus, by characterizing chemical losses during pedogenesis, it is possible to determine the total CO2 that was consumed during pedogenesis. With reasonable estimates of formation time, the gross consumption can be reconfigured as a rate of carbon consumption. This theoretical framework is applied to basalt-parented paleosols from the Picture Gorge Subgroup (Oregon) that span the middle Miocene climatic optimum. The calculations indicate that CO2 consumption is not simply a function of soil formation time and that it is instead controlled by the atmospheric CO2 level. Benthic foraminiferal δ13C values also indicate a carbon burial event at this time that is consistent with the paleosol carbon sequestration estimates. As atmospheric CO2 declined toward the end of the middle Miocene climatic optimum by a factor of three, CO2 consumption by silicate weathering dropped by at least 50%, indicating a strong relationship between the two, even on relatively short timescales (104–105 years).

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SEPM Special Publication

New Frontiers in Paleopedology and Terrestrial Paleoclimatology: Paleosols and Soil Surface Analog Systems

Steven G. Driese
Steven G. Driese
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Lee C. Nordt
Lee C. Nordt
Department of Geology, Baylor University, One Bear Place #97354, Waco, Texas 76798-7354, USA
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SEPM Society for Sedimentary Geology
Volume
104
ISBN electronic:
9781565763036
Publication date:
January 01, 2013

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