The timing and kinematics of Paleozoic peri-Gondwanan terrane accretion along the southern and central Appalachian margin have long been debated. The Silurian–Devonian Concord plutonic suite intruded the western flank of the Carolina superterrane, suggesting east-dipping subduction of ocean crust beneath the Carolina superterrane just prior to accretion, based on Devonian–Mississippian plutonism and metamorphism in the adjacent Laurentian terranes. Geochemical and isotopic data support a subduction-related origin for the Concord plutonic suite, and our geochronologic data reveal the main pulse of plutonism occurred ca. 405 Ma. Our new sensitive high-resolution ion microprobe (SHRIMP) geochronologic data identify a suite of mafic...