Colloid influence on the radionuclide migration from a nuclear waste repository
Colloid formation is discussed as a possible pathway for the radionuclide release from a nuclear waste repository. An assessment of the colloid relevance on radionuclide migration requires insight into the possible colloid generation mechanisms, their stability and mobility under given groundwater conditions. In various experiments dedicated to the investigation of nuclear waste form behaviour in contact with groundwater, colloidal species are observed mainly for the tri- and tetravalent actinides even in rather high ionic strength solutions where destabilization of colloids is expected. Experimental evidence of laboratory and field studies suggests colloid instability in saline groundwater with time. Groundwater of low ionic strength and high pH enhances colloid stability, as demonstrated in various laboratory and field experiments. The results of an in situ colloid characterization study at the Äspö hard rock laboratory in Sweden are discussed as an example. The mechanism of radionuclide interaction with colloids and notably the reversibility of the radionuclide-colloid binding are other key issues of colloid studies. Kinetic stabilization of the radionuclide binding to colloids may lead to a considerable enhancement of the colloid-mediated radionuclide migration. Substantial kinetic inhibition of actinide dissociation from humic colloids has been established by studying the behaviour of natural humic colloid borne U, Th and rare earth elements. Such behaviour might be explained by the incorporation of these elements into inorganic nanoparticles stabilized by humic coating. Spectroscopic evidence for the occurrence of actinide incorporation into colloidal structures is briefly discussed and the importance of considering the kinetics involved in all kinds of colloidal processes is emphasized. The enhanced migration of tri- and tetravalent actinide ions has been observed recently in various in situ dipole tests at the Grimsel hard rock laboratory in Switzerland. Such experimental findings underline the necessity of further studies on the colloid influence on actinide mobility. Moreover, an improved understanding of colloid-rock interaction mechanisms is required, which is essential for the description and prediction of colloid filtration processes.
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Energy, Waste and the Environment: a Geochemical Perspective
This book provides incentives for further development of sustainable fuel cycles through a novel and interdisciplinary approach to an Earth science-related topic. The main focus is on geochemical concepts in immobilizing, isolating or neutralizing waste derived from energy production and consumption. The book also addresses the issue of using some types of energy-derived waste as alternative raw materials. Moreover, it highlights research on how certain wastes can be used for energy production, an increasingly important aspect of modern integrated waste management strategies. The main objectives are to: (a) identify the most serious environmental problems related to various types of power generation and associated waste accumulation; (b) present strategies, based on natural analogue materials, for the immobilization of toxic and radioactive waste components through mineralogical barriers; (c) discuss modern procedures for reuse of waste or certain waste components; and (d) review the importance of geochemical modelling in describing and predicting the interaction between waste and the environment.