Chemical sediments associated with Neoproterozoic glaciation: iron formation, cap carbonate, barite and phosphorite
Paul F. Hoffman, Francis A. Macdonald, Galen P. Halverson, 2011. "Chemical sediments associated with Neoproterozoic glaciation: iron formation, cap carbonate, barite and phosphorite", The Geological Record of Neoproterozoic Glaciations, Emmanuelle Arnaud, Galen P. Halverson, Graham Shields-Zhou
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Orthochemical sediments associated with Neoproterozoic glaciation have prominence beyond their volumetric proportions because of the insights they provide on the nature of glaciation and the records they hold of the environment in which they were precipitated. Synglacial Fe formations are mineralogically simple (haematite jaspilite), and their trace element spectra resemble modern seawater, with a weaker hydrothermal signature than Archaean–Palaeoproterozoic Fe formations. Lithofacies associations implicate subglacial meltwater plumes as the agents of Fe(II) oxidation, and temporal oscillations in the plume flux as the cause of alternating Fe- and Mn-oxide deposits. Most if not all Neoproterozoic examples belong to the older Cryogenian (Sturtian) glaciation. Older and younger Cryogenian (Marinoan) cap carbonates are distinct. Only the younger have well-developed transgressive cap dolostones, which were laid down during the rise in global mean sea level resulting from ice-sheet meltdown. Marinoan cap dolostones have a suite of unusual sedimentary structures, indicating abnormal palaeoenvironmental conditions during their deposition. Assuming the meltdown of ice-sheets was rapid, cap dolostones were deposited from surface waters dominated by buoyant glacial meltwater, within and beneath which microbial activity probably catalysed dolomite nucleation. Former aragonite seafloor cement (crystal fans) found in deeper water limestone above Marinoan cap dolostones indicates carbonate oversaturation at depth, implying extreme concentrations of dissolved inorganic carbon. Barite is associated with a number of Marinoan cap dolostones, either as digitate seafloor cement associated with Fe-dolomite at the top of the cap dolostone, or as early diagenetic void-filling cement associated with tepee or tepee-like breccias. Seafloor barite marks a redoxcline in the water column across which euxinic Ba-rich waters upwelled, causing simultaneous barite titration and Fe(III) reduction. Phosphatic stromatolites, shrub-like structures and coated grains are associated with a glacioisostatically induced exposure surface on a cap dolostone in the NE of the West African craton, but this appears to be a singular occurrence of phosphorite formed during a Neoproterozoic deglaciation.
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In recent years, interest in Neoproterozoic glaciations has grown as their pivotal role in Earth system evolution has become increasingly clear. One of the main goals of the IGCP Project No. 512 was to produce a synthesis of newly available information on Neoproterozoic successions worldwide similar in format to Hambrey & Harland’s (1981) Earth’s pre-Pleistocene Glacial Record. This Memoir therefore consists of a series of overview chapters followed by site-specific chapters. The overview chapters cover key topics including the history of research on Neoproterozoic glaciations, identification of glacial deposits, chemostratigraphic techniques and datasets, palaeomagnetism, biostratigraphy, geochronology and climate modelling. The site specific chapters for 60 successions worldwide include reviews of the history of research on these rocks and up-to-date syntheses of the structural framework, tectonic setting, palaeomagnetic and geochronological constraints, physical, biological, and chemical stratigraphy, and descriptions of the glaciogenic and associated strata, including economic deposits.