The Effect of Volatile Content on the Vesiculation of Submarine Basalts
A shallow environment of formation has been inferred for Kuroko ores in northern Japan at least in part because of their association with vesicular basalt flows. Consideration of the PTX conditions which affect vesiculation demonstrates that reliable depth inferences can be made only if the volatile content of the melt can be independently determined. Vesicle volume and calculated water solubilities are used to estimate the initial water content of the Kuroko basalts. The calculated H 2 O values indicate that most of the vesiculated Kuroko basalts could have been generated at seawater depths up to 4,000 mat total H 2 O contents near 2 wt percent. Analytical data on volatiles in island-arc related lavas, and on the distribution of vesicles in some abyssal basalts, suggest that such volatile concentrations are realistic in environments similar to that of the Kuroko deposits. The vesicular basalts associated with the ores are thus not reliable indicators of the depth of ore formation and do not restrict the Kuroko deposits to depths of less than 1,000 m.
Figures & Tables
This paper consists of three parts. The first is an overview of the geologic history of the Green Tuff region where all Kuroko deposits occur. The second part presents a description of the stratigraphy and an interpretation of the structural and igneous history of the Hokuroku district, the most important Kuroko mining district. The third part is an analysis of the role of submarine calderas in Kuroko genesis.
The sequence and causes of the major geologic events that have occurred in Japan and its vicinity since the Cretaceous are interpreted as follows: (1) an active but shallow-dipping north-northwestward subduction of the Pacific plate under the Asian continent during a period from approximately 130 to 65 m.y. ago resulted in ilmenite series magmatism in the outer zone of Japan, then still a part of mainland Asia; (2) about 65 to 40 m.y. ago, the direction of the subducted Pacific plate changed to westward and the angle of subduction steepened, initiating back-arc spreading in the Japan basin province and migration of Japan away from the Asian mainland until about 30 m.y. ago; (3) during the period 65 to 30 m.y. ago, the basaltic crust created in the Japan basin province was subducted eastward under the Yamato Ridge province, resulting in calc-alkaline and magnetite series igneous activity in the inner zone of Japan; (4) about 25 m.y. ago, the first sea (proto-Japan Sea) was formed in the Japan basin province as a result of the eustatic rise of the sea following cessation of spreading there about 30 m.y. ago; (5) back-arc spreading was active in the Yamato basin province during the period between 25 and 5 m.y. ago, cansing bimodal volcanism and subsidence in the flanking Inner Honshu and Yamato Ridge provinces [the Hokuroku basin (i.e., a Kuroko-bearing basin), Niigata oil field basin, and Akita oil field basin were all fault-bounded, deep (>2,500 m) marine basins created by rapid subsidence of crustal blocks within a few million years around 17 m.y. ago, although Kuroko mineralization and the accumulation of organic matter were not synchronous]; and (6) the dip of the subducted Pacific plate returned to a shallow angle about 5 m.y. ago, causing the cessation of back-arc spreading and the initiation of subsidence of the Yamato basin province and uplift of the flanking Inner Japan and Yamato Ridge provinces. The Green Tuff activity is, therefore, synonymous with the tectonic and igneous activity that accompanied the formation of the Japan Sea and the Japanese islands during the period from ~65 m.y. ago to the present.