Concepts and Models of Dolomitization

Special Publication 28 has its roots in the 22nd Annual Research Symposium of SEPM entitled Concepts and Models of Dolomitization – Their Intricacies and Significance held on April 3,1979 in Houston, Texas as part of the joint annual meetings of AAPG and SEPM. The purpose of that symposium was to express the state-of-the-art of the study of the elusive process(es) of dolomitization. Most of the contributions in this volume are concerned with apparent early, nearsurface dolomitization, either by hypersaline brines, by the marine-meteoric mixing model or some variant thereof, or by both mechanisms where more than one phase or kind of dolomite exists, or where the origin of a particular dolomite is uncertain. Other models and aspects of dolomitization are treated here as well.
The Chemistry of Dolomite Formation I: The Stability of Dolomite
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Published:January 01, 1980
Abstract
An adequate geochemical model of dolomitization requires a knowledge of the stability of dolomite. In theory, the equüibrium constant for the dolomitization reaction can be obtained by a variety of ways: (1) experimental study of equihbrium interaction between calcite, dolomite, and water, (2) calculation from thermodynamic data, and (3) study of the interaction of calcite, dolomite, and water in natural systems. Experimental efforts to determine the calcium-magnesium activity ratio in solutions which have equilibrated with both calcite and dolomite or to determine the ion activity product for dolomite at temperatures less than 200°C have been unsuccessful. The rate of...