Luminescence Microscopy and Spectroscopy: Qualitative and Quantitative Applications

The papers presented in this volume make it clear that luminescence microscopy and spectroscopy are being employed in an ever wider array of geological studies. The editors suggest several ways that luminescence studies can be employed or improved: (1) to assist in the integration of trace element, isotope, fluid inclusion and mineral studies using CL results to assure that the same zones and (or) mineral compositions are utilized; (2) more reliable tracing of zones whether microscopic or of regional extent; (3) better interpretation of diagenetic, mineralization and alteration events because of the control and discrimination of crosscutting relationships and subtle changes in chemistry that often become obvious using luminescence; (4) as a tool for direct detection of rare earth element deposits, Mississippi Valley type Pb-Zn ores and in some cases oil reservoirs; (5) introduction of standard materials and methods for calibrating spectrometers and possibly increasing the uniformity of subjective observations; (6) improvements in instrumentation to diminish thermal quenching effects at the same time gains are necessary in the level of activation of luminescence and in the quality of the microscopic image transmitted to the observer; (7) more efforts at experimental determination of the causes of luminescence and their interpretation relative to conditions that exist in natural systems.
Using Cathodoluminescence to Map Regionally Zoned Carbonate Cements Occurring in Diagenetic Aureoles Above Oil Reservoirs: Initial Results from the Velma Oil Field, Oklahoma:
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Published:January 01, 1991
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CiteCitation
Charles E. Barker, Debra K. Higley, Mary C. Dalziel, 1991. "Using Cathodoluminescence to Map Regionally Zoned Carbonate Cements Occurring in Diagenetic Aureoles Above Oil Reservoirs: Initial Results from the Velma Oil Field, Oklahoma:", Luminescence Microscopy and Spectroscopy: Qualitative and Quantitative Applications, Charles E. Barker, Robert C. Burruss, Otto C. Kopp, Hans G. Machel, Donald J. Marshall, Paul Wright, Helen Y. Colbum
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Abstract:
Mappable variations in the metallic ion concentration of late diagenetic carbonate cements at the surface above Velma oil field can be correlated to a qualitative measure of cathodoluminescence (CL). This proposed measure, the carbonate CL index or CCI, compares trace element quencher and activators of CL in carbonates to visual estimates of CL intensity.
The late diagenetic aureole at Velma is well developed. In surface sandstone, the aureole contains abundant Fe sulfides and associated ferroan carbonate cement which imparts a dark-reddish-brown color to the rock. The aureole is surrounded by Fe-poor sandstone. Prior studies of the Permian siliciclastic rocks...